Abstract
Small covalent nitrile oxides are important transient species in organic synthesis and widely used especially for dipolar cycloaddition reactions. Due to their instability, their isolation and characterization are challenging. This review focuses on the generation, spectroscopy, structural properties, and synthetic application of small nitrile oxides, XCNO, where the X substituent group is smaller than five atoms, viz. X= hydrogen, halogen, pseudohalogen, alkyl, vinyl, ethynyl, or nitro.
Keywords: Nitrile oxides, synthesis, spectroscopy, stucture, applications, reactive dipolarophiles, Mukaiyama, –, Hoshino method, silyloxy, pyrrolidine, morpholine, glyoximes, Organosilicon halides, pseudohalides, Acrylonitrile oxide
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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