Abstract
In the present review we attempt to systematize and generalize the available data on prototropy in imidoylphosphonates containing α-hydrogen atoms in the N- or C-alkyl groups of the C=N bond. Prototropic transitions in C=N-CH triad of imidoylphosphonates leading to biorelevant α-aminophosphonates are in main focus of the review. Central to this endeavour is elucidation of the effect that the phosphoryl or phosphonium moiety exerts on prototropy in the phosphorylated 2-azaallylic triad.
Keywords: imidoylphosphonates, imidoyl chlorides, aminophosphonates, proton transfer, stereoselectivity, rearrangements
Current Organic Chemistry
Title: Prototropic Isomerizations in the 2-Azaallylic Triad of Imidoylphosphonates
Volume: 14 Issue: 12
Author(s): Petro P. Onys'ko, Yuliya V. Rassukana and Oleksii A. Synytsya
Affiliation:
Keywords: imidoylphosphonates, imidoyl chlorides, aminophosphonates, proton transfer, stereoselectivity, rearrangements
Abstract: In the present review we attempt to systematize and generalize the available data on prototropy in imidoylphosphonates containing α-hydrogen atoms in the N- or C-alkyl groups of the C=N bond. Prototropic transitions in C=N-CH triad of imidoylphosphonates leading to biorelevant α-aminophosphonates are in main focus of the review. Central to this endeavour is elucidation of the effect that the phosphoryl or phosphonium moiety exerts on prototropy in the phosphorylated 2-azaallylic triad.
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P. Onys'ko Petro, V. Rassukana Yuliya and A. Synytsya Oleksii, Prototropic Isomerizations in the 2-Azaallylic Triad of Imidoylphosphonates, Current Organic Chemistry 2010; 14 (12) . https://dx.doi.org/10.2174/138527210791330440
DOI https://dx.doi.org/10.2174/138527210791330440 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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