Synthesis, Structural Characterization, Spectroscopic and Electrochemical Studies of N,N-bis[(2,4-dimethoxyphenyl) methylidene]butane-1,4-diamine

Title: Synthesis, Structural Characterization, Spectroscopic and Electrochemical Studies of N,N-bis[(2,4-dimethoxyphenyl) methylidene]butane-1,4-diamine

Volume: 14 Issue: 3

Author(s): Mustafa Dolaz, Vickie McKee, Aysegul Golcu and Mehmet Tumer

Affiliation:

Abstract: In this study, the title compound, N,N-bis[(2,4-dimethoxyphenyl)methylidene]butane-1,4-diamine (L), was prepared and characterized by analytical and spectroscopic methods. The analytical data of the Schiff base ligand (L) confirms the proposed structure. The conductance value indicates that the ligand is non-electrolyte. The electrochemical properties of the ligand (L) are dependent on irreversible and quasi-reversible redox waves in the anodic and cathodic regions, due to oxidation and reduction. The single crystal of the ligand (L) was obtained from MeOH solution. Space group and crystal system of the ligand are P21/C and monoclinic, respectively. Unit cell dimensions of the ligand are a=4.0647(2) Å, b=17.4186 (10) Å, c= 13.8982(8) Å and β= 94.325 (1) .

Cite this article as:

Dolaz Mustafa, McKee Vickie, Golcu Aysegul and Tumer Mehmet, Synthesis, Structural Characterization, Spectroscopic and Electrochemical Studies of N,N-bis[(2,4-dimethoxyphenyl) methylidene]butane-1,4-diamine, Current Organic Chemistry 2010; 14 (3) . https://dx.doi.org/10.2174/138527210790231946