Abstract
Nowadays palladium-catalyzed C–H bond activation is a useful approach for the synthetic transformation of organic compounds due to step economy, the use of non-prefunctionalized substrates and reduced chemical wastes. Among the various synthetic strategies, palladium catalyzed intra and inter-molecular C–H bond activation has recently drawn a lot of interest to synthesize the decorated π-conjugated polycyclic aromatic hydrocarbon. In this review, we have focused on recent progress along with previous strategies to synthesize various polynuclear aromatic hydrocarbons (PAHs) by the use of Pd-catalyzed C–H bond activation. We have also discussed the mechanistic details of the reaction intra and inter-molecular C–H bond activation.
Graphical Abstract
Current Organic Chemistry
Title:Synthesis of Polynuclear Aromatic Hydrocarbons by Palladium-catalyzed C-H Bond Functionalization
Volume: 28 Issue: 18
Author(s): Mitali Dewan, Sachinath Bera, Shubhankar Samanta, Debasish Kundu*Rathin Jana*
Affiliation:
- Department of Chemistry, Government General Degree College, Mangalkote, India
- Department of Chemistry, Shahid Matangini Hazra Govt. General Degree College for Women (Affiliated to Vidyasagar University), Tamluk, Purba Medinipur, W.B. India
Abstract: Nowadays palladium-catalyzed C–H bond activation is a useful approach for the synthetic transformation of organic compounds due to step economy, the use of non-prefunctionalized substrates and reduced chemical wastes. Among the various synthetic strategies, palladium catalyzed intra and inter-molecular C–H bond activation has recently drawn a lot of interest to synthesize the decorated π-conjugated polycyclic aromatic hydrocarbon. In this review, we have focused on recent progress along with previous strategies to synthesize various polynuclear aromatic hydrocarbons (PAHs) by the use of Pd-catalyzed C–H bond activation. We have also discussed the mechanistic details of the reaction intra and inter-molecular C–H bond activation.
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Cite this article as:
Dewan Mitali, Bera Sachinath, Samanta Shubhankar, Kundu Debasish*, Jana Rathin*, Synthesis of Polynuclear Aromatic Hydrocarbons by Palladium-catalyzed C-H Bond Functionalization, Current Organic Chemistry 2024; 28 (18) . https://dx.doi.org/10.2174/0113852728283702240605113835
DOI https://dx.doi.org/10.2174/0113852728283702240605113835 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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