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Current Nanoscience

Editor-in-Chief

ISSN (Print): 1573-4137
ISSN (Online): 1875-6786

Research Article

Poly-Thionine/ SWCNT Nanocomposite Coated Electrochemical Sensor for Determination of Vitamin C

In Press, (this is not the final "Version of Record"). Available online 23 February, 2024
Author(s): Sangeetha Dhanapalan, Vasanth Magesh, Raji Atchudan, Sandeep Arya, Dhanraj Ganapathy, Deepak Nallaswamy and Ashok Sundramoorthy*
Published on: 23 February, 2024

DOI: 10.2174/0115734137289697240216070503

Price: $95

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Abstract

Background: The electrochemical sensors convert biological or chemical information, such as analyte concentration or a biomolecular (biochemical receptor) interaction, into electrical signals. In this paper, we describe the development of a poly-thionine/ single-walled carbon nanotube (P-Th/SWCNT) composite for the electrochemical detection of ascorbic acid (vitamin C).

Methods: To improve electrochemical performance, we attempted to electro-polymerize the thionine monomers, an essential chemical building block, directly on the surface of singlewalled carbon nanotubes (SWCNT).

Results: Field Emission Scanning electron microscopy (FESEM) and energy dispersive spectroscopy (EDS) results revealed that a complex structure of the P-Th/SWCNT was formed. The presence of carbon (C), oxygen (O), nitrogen (N), and sulfur (S) components was confirmed, which indicated the effective fusion of poly-thionine onto SWCNT. Moreover, the X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy confirmed the composite formation. Utilizing cyclic voltammetry, the composite's electrochemical behavior was examined.

Conclusions: Excellent electrocatalytic activity towards the oxidation of ascorbic acid was shown by the P-Th/SWCNT composite. The as-prepared P-Th/SWCNT composite-modified sensor can detect ascorbic acid in food, medical, and pharmaceutical samples.


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