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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Letter Article

Cholapod and Cholaphanes for Recognition of Anions

Author(s): Mamta Chahar*, Sarita Khaturia* and Anjali Bishnoi

Volume 27, Issue 21, 2023

Published on: 07 December, 2023

Page: [1833 - 1841] Pages: 9

DOI: 10.2174/0113852728272205231122055645

Price: $65

Abstract

Deoxycholic and cholic acid-based receptors 6, 13, and 16 containing imidazolium groups were synthesized, and their properties as anion receptors have been evaluated. Cholaphanes 13 and 16 exhibited moderate binding selectivity and affinity for fluoride ions, while cholapod 6 showed low binding selectivity and affinity for chloride ions due to the presence of a nitro group in the imidazolium ring. The H-bonding interactions involve C-2 protons of imidazolium ring with anion. The detection of halide ions is revealed by the binding constant through the 1H NMR titration experiment.

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