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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Research Article

Synthesis of Triamantane by Skeletal Transformation of Hexa- and Heptacyclooctadecanes under the Action of Ionic Liquids

Author(s): Rishat I. Aminov*

Volume 27, Issue 13, 2023

Published on: 05 October, 2023

Page: [1191 - 1198] Pages: 8

DOI: 10.2174/1385272827666230817141209

Price: $65

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Abstract

New methods have been developed for the synthesis of the third representative of the homologous series of diamond-like hydrocarbons, triamantane, with a yield of up to 78%, by skeletal isomerization of iso-compositional endo-endo- and exo-exo-heptacyclo [9.6.1.02,10.03,8.04,6.05,9.012,17]octadecanes under the action of aluminate ionic liquids. For the first time, the synthesis and transformation of new C18H26 hydrocarbons - endo-exo- and exo-exo-hexacyclo[8.6.1.15,8.02,9.03,7.011,16]octadecanes into triamantane was carried out. It has been established that for the successful conversion of polycyclic hydrocarbons of the composition С18H26 containing two more hydrogen atoms in the molecule than in triamantane, the addition of Pd/C to the ionic liquid is necessary.

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