Login Register Cart 0
Generic placeholder image

Current Microwave Chemistry

Editor-in-Chief

ISSN (Print): 2213-3356
ISSN (Online): 2213-3364

Back
Journal Home About Journal Editorial Board Journal Insight Current Issue Volumes/Issues
Subscribe
General Research Article

Ultrasonic Study of Novel Polymer Dextran in Aqueous Media at 12 MHz

Author(s): Subhraraj Panda*

Volume 10, Issue 2, 2023

Published on: 20 September, 2023

Page: [237 - 243] Pages: 7

DOI: 10.2174/2213335610666230810094605

Price: $65

conference banner
Abstract

Background: The characteristics of matter and the dynamics of molecular processes are examined by acoustic approaches. The primary techniques in molecular acoustics are the measurement of sound speed and sound absorption, as well as the relationship between these quantities and different physical variables including pressure, temperature, and wave frequency. Molecular acoustics emerged as a separate field in the 1930s. When it was discovered that many substances disperse the speed of sound during the transmission of sound waves through them and that the classical law, which states that the coefficient of absorption is proportional to the square of the frequency, however, it does not adequately describe how sound is absorbed.

Objective: The ultrasonic technique is employed because it is one of the most popular techniques, which is very easy to use, and provides precise velocity results. With careful analysis of the results, the correlation between solute and solvent was discovered. In the pharmaceutical, agricultural, and cosmetics industries, dextran and its derivatives from a few select strains have found a wide range of uses. This is why we have chosen it for our study. For assessing the impact of temperature and concentration on the aqueous medium containing the polymer dextran, ultrasonic properties are crucial. Pycnometer, Ostwald viscometer, and ultrasonic interferometer were used respectively to measure density (ρ), viscosity (η), and ultrasonic speed (u) at "303 K, 308 K, 313 K, 318 K, and 323 K." The experimental parameters are used to determine the acoustic parameters "adiabatic compressibility, Intermolecular free length, relaxation time, acoustic impedance, and Gibb's free energy".

Methods: To measure the density, viscosity, and ultrasonic velocity of the solution using a pycnometer, an Ostwald's viscometer, and an ultrasonic interferometer, and to calculate the thermo acoustical parameters based on the measured parameters.

Results: Applications for examining the physico-chemical behaviour of aqueous dextran using ultrasound include understanding the nature of molecular interactions.

Conclusion: It was investigated how concentration and temperature affected the thermoacoustic characteristics of aqueous dextran. Hydrogen bonds, charge transfer complexes, and the dissolution of hydrogen bonds and complexes are only a few examples of the forces that exist between molecules and how the analysis has interpreted their nature. Weak intermolecular forces exist.

Other: Recent developments in ultrasonic techniques have made them an effective tool for evaluating information regarding the physical and chemical behaviour of liquid molecules.

« Previous Next »
Graphical Abstract

[1]
Zorȩbski, E.; Kulig, A. Densities, speeds of sound, and isentropic compressibilities for binary mixtures of 1, 2-ethanediol with 2-ethyl-1-hexanol, 1-heptanol, or ethanol at the temperature 298.15 K and densities for mixtures of 1, 2-ethanediol with 1-nonanol at the temperatures (293.15 and 298.15). K. J. Chem. Eng. Data, 2010, 55(9), 3937-3941.
[http://dx.doi.org/10.1021/je9010882]
[2]
Nithiyanantham, S.; Palaniappan, L. Acousti Cal Studi Es On Som E Di Sacchari Des (Sucrose, Lactose, M Altose) In Aqueousmedia At Room Temperature. Metals Mater. Proc., 2008, 20(3), 203-208.
[3]
Kaur, B.; Juglan, K.C. Acoustic parameter investigation of polyvinyl acetate with acetic acid using ultrasonic technique. J. Polymer Eng., 2013, 33(9), 851-856.
[4]
Singh, S.; Talukdar, M.; Dash, U.N. Ultrasonic studies on paracetamol in aqueous solutions of sodium salicylate and nicotinamide. J. Mol. Liq., 2018, 249, 815-824.
[http://dx.doi.org/10.1016/j.molliq.2017.11.099]
[5]
Panda, S. Molecular interaction of novel polymer dextran with 1 (N) sodium hydroxide solution: Ultrasonic studies. Asia- Pacific. J. Sci. Technol., 2022, 27(6), 1-7.
[6]
Zolkiflee, N.F.; Affandi, M.M.R.M.M.; Majeed, A.B.A. Molecular dynamics and related solution chemistry of lovastatin in aqueous solution of arginine: Viscometric analysis. J. Mol. Liq., 2019, 279, 386-391.
[http://dx.doi.org/10.1016/j.molliq.2019.01.102]
[7]
Tiwari, S.; Kusmariya, B.S.; Tiwari, A.; Pathak, V.; Mishra, A.P. Acoustical and viscometric studies of buspirone hydrochloride with cobalt(II) and copper(II) ions in aqueous medium. J. Taibah Univ. Sci., 2017, 11(1), 101-109.
[http://dx.doi.org/10.1016/j.jtusci.2015.10.012]
[8]
Kaur, K.; Juglan, K.C. Studies of molecular interaction in the binary mixture of chloroform and methanol by using ultrasonic technique. Pharma Chem., 2015, 7(2), 160-167.
[9]
Panda, S. Molecular interaction of polymer dextran in sodium hydroxide through evaluation of thermo acoustic parameters. Indian J. Pharmaceut. Edu. Res., 2020, 54(3), 630-636.
[http://dx.doi.org/10.5530/ijper.54.3.112]
[10]
Patnaik, P.; Chakraborty, N.; Kaur, P.; Juglan, K.C.; Kumar, H. Thermodynamic and acoustic investigation of d-panthenol in homologous series of polyethylene glycol at different temperatures. In: Advances in Functional and Smart Materials; Springer: Singapore, 2023, pp. 403-424.
[http://dx.doi.org/10.1007/978-981-19-4147-4_41]
[11]
Kim, D.; Robyt, J.F.; Lee, S.Y.; Lee, J.H.; Kim, Y.M. Dextran molecular size and degree of branching as a function of sucrose concentration, pH, and temperature of reaction of Leuconostoc mesenteroides B-512FMCM dextransucrase. Carbohydr. Res., 2003, 338(11), 1183-1189.
[http://dx.doi.org/10.1016/S0008-6215(03)00148-4] [PMID: 12747860]
[12]
Kim, D.M.; Seo, E.S.; Lee, J.H.; Kang, H.K.; Cho, J.Y. 2004, Potential Industrial Applications and Evolution of Carbohydrolases and Glycansucrases. Proceedings of the Korean Society for Applied Microbiology Conference.The Korean Society for Microbiology and Biotechnology., , pp. 215-218.
[13]
Li, X.; Wang, X.; Meng, X.; Dijkhuizen, L.; Liu, W. Structures, physico-chemical properties, production and (potential) applications of sucrose-derived α-d-glucans synthesized by glucansucrases. Carbohydr. Polym., 2020, 249, 116818.
[http://dx.doi.org/10.1016/j.carbpol.2020.116818] [PMID: 32933666]
[14]
Panda, S. Thermoacoustical Analysis of Polymer Dextran at Different Frequencies. Bulgarian J. Phy., 2022, 49(2)
[15]
Panda, S. Molecular interaction study of binary liquid solution using ultrasonic technique. Recent Innov. Chem. Eng., 2022, 15(2), 138-146.
[http://dx.doi.org/10.2174/2405520415666220707142909]
[16]
Panda, S. Thermoacoustical parameters of dextran polymer in sodium hydroxide solutions. Songklanakarin J. Sci. Technol., 2022, 44(4)
[17]
Panda, S.; Mahapatra, A.P. Intermolecular interaction of dextran with urea. Int. J. Innov. Technol. Explor. Eng., 2019, 8(11), 742-748.
[http://dx.doi.org/10.35940/ijitee.K1445.0981119]
[18]
Venkatakshmi, V.; Gowrisankar, M.; Venkateswarlu, P.; Reddy, K.S. Density, ultrasonic velocity, viscosity and their excess parameters of the binary mixtures of 2-methyl aniline with 1-alkanols (C3-C8) at different temperatures. Int. J. Phy., 2013, 3, 33-44.
[19]
Gowrisankar, M.; Venkateswarlu, P.; Sivakumar, K.; Sivarambabu, S. Thermodynamics of amine + ketone mixtures: Volumetric, speed of sound data and viscosity at 303.15 K and 308.15 K for the binary mixtures of N,N-diethylaniline + aliphatic ketones (C3–C5) + 4-methyl-2-pentanone. Arab. J. Chem., 2017, 10, S2625-S2636.
[http://dx.doi.org/10.1016/j.arabjc.2013.09.042]
[20]
Panda, S.; Mahapatra, A.P. Molecular interaction of dextran with urea through Ultrasonic technique. Clay Res., 2019, 38(1), 35-42.
[21]
Fort, R.J.; Moore, W.R. Adiabatic compressibilities of binary liquid mixtures. Trans. Faraday Soc., 1965, 61, 2102-2111.
[http://dx.doi.org/10.1039/tf9656102102]
[22]
Panda, S. Analysis of Aqueous Dextran: An Ultrasonic Study. Curr. Microw. Chem., 2022, 9(1), 30-36.
[http://dx.doi.org/10.2174/2213335609666220324144409]
[23]
Kaur, M.; Pathania, V.; Vermani, B.K.; Anand, V.; Gill, D.S. Ultrasonic velocity and thermoacoustic parameters for copper(I) nitrates in dimethylsulfoxide with pyridine as a Co-Solvent at 298 K. Curr. Phys. Chem., 2022, 12(2), 136-158.
[http://dx.doi.org/10.2174/1877946812666220331122201]
[24]
Sharma, A.K.; Sharma, R.; Gangwal, A. Ultrasonic studies and acoustic parameters of complexes containing copper surfactants with 2-amino-6-methyl benzo-thiazole. Curr. Phys. Chem., 2019, 8(3), 222-229.
[http://dx.doi.org/10.2174/1573412914666181003151414]
[25]
Dudhe, V.G.; Tabhane, V.A.; Chimankar, O.P.; Dudhe, C.M. Study on molecular interaction of aqueous ascorbic acid (Vitamin C) at 293k. Univ. J. Appl. Sci., 2014, 2(2), 53-56.
[http://dx.doi.org/10.13189/ujas.2014.020203]
[26]
Panda, S. Thermo-acoustic parameters of polymer dextran with aqueous sodium hydroxide: An ultrasonic study. Curr. Mater. Sci., 2023, 16(2), 217-224.
[http://dx.doi.org/10.2174/2666145415666220817124330]

Rights & Permissions Print Cite
© 2024 Bentham Science Publishers | Privacy Policy