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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Synthesizing Conducting Poly(Aniline-co-Aminoacetophenone) Nanocomposites based on Polyhydroxy Iron Cation–modified Clay

Author(s): Yasmine Rekrak, Ahmed Yahiaoui, Aicha Hachemaoui, Abdelkader Dehbi*, Leila Mouacher, Abdelkarim Bendoukha Reguig and Abdelhamid Ismail Mourad

Volume 20, Issue 10, 2023

Published on: 08 June, 2023

Page: [958 - 966] Pages: 9

DOI: 10.2174/1570178620666230523160440

Price: $65

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Abstract

Conductive clay–polymer nanocomposites were prepared via the in situ polymerization of aminoacetophenone and/or aniline monomers (at initial “aminoacetophenone:aniline”) in the presence of polyhydroxy iron cation–modified montmorillonite (MMT-PIC). Fourier transform infrared spectroscopy analysis demonstrated the characteristic bands of the MMT-PIC polymers/copolymers. The morphological properties analyzed and imaged through X-ray diffraction and scanning electron microscopy, respectively, displayed an increasing interlayer distance with the mass loading of PIC and poly(aminoacetophenone-co-aniline) (poly(AAP-co-ANI)), affording intercalated nanocomposites. Energy-dispersive X-ray spectroscopy measurements revealed that the clay experienced a cation exchange of sodium by the PIC, and poly(AAP-co-ANI) was present in large amounts on the nanocomposite surface. The electrical conductivity of the obtained nanocomposites was 5.760 × 10−5 S⋅cm−1. Moreover, the electrochemical behavior of the polymers extracted from the nanocomposites was studied via cyclic voltammetry; the redox processes indicated that the polymerization into activated carbon produced electroactive polymers.

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