Generic placeholder image

Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Research Article

Folic Acid Promoted the Coupling Reaction of Epoxides and CO2

Author(s): Mengliang Chai, Fengtian Wu* and Ling Wu*

Volume 20, Issue 4, 2023

Published on: 08 December, 2022

Page: [370 - 375] Pages: 6

DOI: 10.2174/1570178620666221107143338

Price: $65

Abstract

The process of hydrogen bond donor accelerating the cycloaddition of epoxides with CO2 is green access to high economic value cyclocarbonate derivatives. However, hydrogen bond donor still has certain limitations such as poor biocompatibility and narrow substrate scope. Our group found that folic acid could promote the coupling reaction of epoxides and CO2 through hydrogen-bonding. The reaction was used to synthesize various cyclocarbonate derivatives in good to high yields with the aid of folic acid and TBAB. In addition, benzoic acids and 2,4-quinazoline dione were synthesized in the presence of CuCl2/folic acid and PdCl2/folic acid, respectively. The reaction mechanism was proposed based on previous reports and control experiments.

Graphical Abstract

[1]
Lu, X.B.; Darensbourg, D. J. Chem. Soc. Rev., 2012, 41(4), 1462-1484.
[http://dx.doi.org/10.1039/C1CS15142H] [PMID: 21858339]
[2]
Gorji, Z.E.; Khodadadi, A.A.; Riahi, S.; Repo, T.; Mortazavi, Y.; Kemell, M. J. Environ. Sci. (China), 2023, 126, 408-422.
[http://dx.doi.org/10.1016/j.jes.2022.04.046]
[3]
Prasad, D.; Patil, K.N.; Chaudhari, N.K.; Kim, H.; Nagaraja, B.M.; Jadhav, A.H. Catal. Rev., Sci. Eng., 2022, 64(2), 356-443.
[http://dx.doi.org/10.1080/01614940.2020.1812212]
[4]
Wu, L.; Zeng, Q.; Hu, P.; Zong, T.; Wu, F. Lett. Org. Chem., 2021, 18(10), 812-816.
[http://dx.doi.org/10.2174/1570178617999201110115648]
[5]
Yao, J.; Sheng, M.; Bai, S.; Su, H.; Shang, H.; Deng, H. Sun. J. Catal. Lett., 2022, 152(3), 781-790.
[http://dx.doi.org/10.1007/s10562-021-03667-9]
[6]
Khan, M.U.; Khan, S.U.; Kiriratnikom, J.; Zareen, S.; Zhang, X. Chin. Chem. Lett., 2022, 33(2), 1081-1086.
[http://dx.doi.org/10.1016/j.cclet.2021.06.002]
[7]
Zhang, J.; Zou, M.; Li, Q.; Dai, W.; Wang, D.; Zhang, S.; Li, B.; Yang, L.; Luo, S.; Luo, X. Appl. Surf. Sci., 2022, 572151408
[http://dx.doi.org/10.1016/j.apsusc.2021.151408]
[8]
Fiorani, G.; Guo, W.; Kleij, A.W. Green Chem., 2015, 17(3), 1375-1389.
[http://dx.doi.org/10.1039/C4GC01959H]
[9]
Xie, Y.; Sun, Q.; Fu, Y.; Song, L.; Liang, J.; Xu, X.; Wang, H.; Li, J.; Tu, S.; Lu, X.; Li, J. J. Mater. Chem. A Mater. Energy Sustain., 2017, 5(48), 25594-25600.
[http://dx.doi.org/10.1039/C7TA09656A]
[10]
Dai, Z.; Sun, Q.; Liu, X.; Guo, L.; Li, J.; Pan, S.; Bian, C.; Wang, L.; Hu, X.; Meng, X.; Zhao, L.; Deng, F.; Xiao, F.S. ChemSusChem, 2017, 10(6), 1186-1192.
[http://dx.doi.org/10.1002/cssc.201601375] [PMID: 27860370]
[11]
Tang, L.; Zhang, S.; Wu, Q.; Wang, X.; Wu, H.; Jiang, Z. J. Mater. Chem. A Mater. Energy Sustain., 2018, 6(7), 2964-2973.
[http://dx.doi.org/10.1039/C7TA09082J]
[12]
Liu, F.; Gu, Y.; Xin, H.; Zhao, P.; Gao, J.; Liu, M. ACS Sustain. Chem. Eng., 2019, 7(19), 16674-16681.
[http://dx.doi.org/10.1021/acssuschemeng.9b04090]
[13]
Ejarque, D.; Calvet, T.; Font-Bardia, M.; Pons, J. CrystEngComm, 2022, 24(15), 2808-2824.
[http://dx.doi.org/10.1039/D1CE01584B]
[14]
Ejarque, D.; Calvet, T.; Font-Bardia, M.; Pons, J. CrystEngComm, 2021, 23(35), 6199-6213.
[http://dx.doi.org/10.1039/D1CE00833A]
[15]
Sun, H.; Zhang, D. J. Phys. Chem. A, 2007, 111(32), 8036-8043.
[http://dx.doi.org/10.1021/jp073873p]
[16]
Fanjul-Mosteirín, N.; Jehanno, C.; Ruipérez, F.; Sardon, H.; Dove, A.P. ACS Sustain. Chem. Eng, 2019, 7(12), 10633-10640.
[http://dx.doi.org/10.1021/acssuschemeng.9b01300]
[17]
Zhang, Z.; Fan, F.; Xing, H.; Yang, Q.; Bao, Z.; Ren, Q. ACS Sustain. Chem. Eng, 2017, 5(4), 2841-2846.
[http://dx.doi.org/10.1021/acssuschemeng.7b00513]
[18]
Castro-Osma, J.A.; Martínez, J.; de la Cruz-Martínez, F.; Caballero, M.P.; Fernández-Baeza, J.; Rodríguez-López, J.; Otero, A.; Lara-Sánchez, A. Tejeda. J. Catal. Sci. Technol., 2018, 8(7), 1981-1987.
[http://dx.doi.org/10.1039/C8CY00381E]
[19]
Wu, X.; Chen, C.; Guo, Z.; North, M.; Whitwood, A.C. ACS Catal., 2019, 9(3), 1895-1906.
[http://dx.doi.org/10.1021/acscatal.8b04387]
[20]
Liu, N.; Xie, Y.F.; Wang, C.; Li, S.J.; Wei, D.; Li, M.; Dai, B. ACS Catal., 2018, 8(11), 9945-9957.
[http://dx.doi.org/10.1021/acscatal.8b01925]
[21]
Li, Y.; Dominelli, B.; Reich, R.M.; Liu, B.; Kühn, F.E. Catal. Commun., 2019, 124, 118-122.
[http://dx.doi.org/10.1016/j.catcom.2019.03.012]
[22]
Wu, F.; Lin, Y. Appl. Organomet. Chem., 2020, 34(3)e5427
[23]
Wu, F.; Wu, L.; Cui, C. Tetrahedron, 2021, 83131965
[http://dx.doi.org/10.1016/j.tet.2021.131965]
[24]
Piquereau, J.; Boitard, S.E.; Ventura-Clapier, R.; Mericskay, M. Int. J. Mol. Sci., 2021, 23(1), 30.
[http://dx.doi.org/10.3390/ijms23010030] [PMID: 35008448]
[25]
Sopeña, S.; Martin, E.; Escudero-Adán, E.C.; Kleij, A.W. ACS Catal., 2017, 7(5), 3532-3539.
[http://dx.doi.org/10.1021/acscatal.7b00475]
[26]
Dai, W.; Yang, W.; Zhang, Y.; Wang, D.; Luo, X.; Tu, X. J. CO2 Util., , 2017, 17, 256-262.
[27]
Wang, Y.; Liu, Y.; Su, Q.; Li, Y.; Deng, L.; Dong, L.; Fu, M.; Liu, S.; Cheng, W. J. CO2 Util., , 2022, 60101976,
[28]
Ji, L.; Luo, Z.; Zhang, Y.; Wang, R.; Ji, Y.; Xia, F.; Gao, G. Molecular Catalysis, 2018, 446, 124-130.
[http://dx.doi.org/10.1016/j.mcat.2017.12.026]
[29]
Song, B.; Cao, N.; Zhang, J. Xie. J.Molecular. Catalysis., 2021, 516111981
[http://dx.doi.org/10.1016/j.mcat.2021.111981]
[30]
Wang, Y.; Jiang, X.; Wang, B. Chem. Commun. (Camb.), 2020, 56(92), 14416-14419.
[http://dx.doi.org/10.1039/D0CC06451C] [PMID: 33146176]
[31]
Sharafi-Kolkeshvandi, M.; Nikpour, F. Chin. Chem. Lett., 2012, 23(4), 431-433.
[http://dx.doi.org/10.1016/j.cclet.2012.01.027]

Rights & Permissions Print Cite
© 2025 Bentham Science Publishers | Privacy Policy
Request history8.2.27PHP Version353msRequest Duration28MBMemory UsageGET article/{article_id}/{param?}Route
  • warninglog[06:17:18] LOG.warning: Optional parameter $article_id declared before required parameter $request i...
  • warninglog[06:17:18] LOG.warning: Function strftime() is deprecated in /home/alphaeurekaselec/public_html/stor...
  • warninglog[06:17:18] LOG.warning: trim(): Passing null to parameter #1 ($string) of type string is deprecated ...
  • warninglog[06:17:18] LOG.warning: Function strftime() is deprecated in /home/alphaeurekaselec/public_html/stor...
  • Booting (108ms)time
  • Application (245ms)time
  • 1 x Application (69.51%)
    245ms
    1 x Booting (30.49%)
    108ms
    14 templates were rendered
    • articlearticle.blade.php#?blade
    • includes.article_top_bannerarticle_top_banner.blade.php#?blade
    • includes.article_referencearticle_reference.blade.php#?blade
    • export_citation_formexport_citation_form.blade.php#?blade
    • includes.article_bottom_bannerarticle_bottom_banner.blade.php#?blade
    • includes.inc_related_journalsinc_related_journals.blade.php#?blade
    • includes.inc_related_ebooksinc_related_ebooks.blade.php#?blade
    • includes.journal_rightmenujournal_rightmenu.blade.php#?blade
    • includes.journal_right_bannerjournal_right_banner.blade.php#?blade
    • layouts.appapp.blade.php#?blade
    • layouts._login_access_login_access.blade.php#?blade
    • layouts._header_header.blade.php#?blade
    • layouts._main_menu_main_menu.blade.php#?blade
    • layouts._footer_menu_footer_menu.blade.php#?blade
    uri
    GET article/{article_id}/{param?}
    middleware
    web, check_user_access
    controller
    App\Http\Controllers\ArticleController@GetArticleDetails
    namespace
    App\Http\Controllers
    where
    as
    article
    file
    app/Http/Controllers/ArticleController.php:1974-2510
    36 statements were executed, 4 of which were duplicates, 32 unique. Show only duplicated146ms
    • Connection Establishedalphaeurekaselec_live_10_06_2022UserAccessCheck.php#24
      Backtrace
      • 9. middleware::check_user_access:24
      • 10. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
      • 11. vendor/laravel/framework/src/Illuminate/Routing/Middleware/SubstituteBindings.php:50
      • 12. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
      • 13. vendor/laravel/framework/src/Illuminate/Foundation/Http/Middleware/VerifyCsrfToken.php:88
    • INSERT INTO visitor_ip_address (ip_address,visitor_agent,visitor_count, created_on,updated_on) VALUES ('316409794','',1,1740550638,1740550638) ON DUPLICATE KEY UPDATE visitor_count=visitor_count + 1, updated_on=1740550638
      1.02msalphaeurekaselec_live_10_06_2022UserAccessCheck.php#24
      Backtrace
      • 11. middleware::check_user_access:24
      • 12. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Middleware/SubstituteBindings.php:50
      • 14. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
      • 15. vendor/laravel/framework/src/Illuminate/Foundation/Http/Middleware/VerifyCsrfToken.php:88
    • INSERT INTO visitor_ip_address_detail (ip_address,visitor_url,visitor_count, created_on,updated_on) VALUES ('316409794','/article/127430',1,1740550638,1740550638)
      210μsalphaeurekaselec_live_10_06_2022UserAccessCheck.php#27
      Backtrace
      • 11. middleware::check_user_access:27
      • 12. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Middleware/SubstituteBindings.php:50
      • 14. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
      • 15. vendor/laravel/framework/src/Illuminate/Foundation/Http/Middleware/VerifyCsrfToken.php:88
    • (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_journal_volume_trail WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_journal_volume_corporate WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_journal_volume_token WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_ebook_volume_trail WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_ebook_volume_corporate WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_ebook_volume_token WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_issue_trail WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_issue_corporate WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_issue_token WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_article_trail WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_article_corporate WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_article_token WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_chapter_trail WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_chapter_corporate WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_chapter_token WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) union (select `user_id`, `to_ip`, `from_ip` from (select user_id, to_ip, from_ip FROM user_access_disease_corporate WHERE to_ip >= 316409794 ORDER BY to_ip ASC LIMIT 1) as `tjv` where `from_ip` <= 316409794) limit 1
      12.23msalphaeurekaselec_live_10_06_2022UserAccess.php#784
      Bindings
      • 0: 316409794
      • 1: 316409794
      • 2: 316409794
      • 3: 316409794
      • 4: 316409794
      • 5: 316409794
      • 6: 316409794
      • 7: 316409794
      • 8: 316409794
      • 9: 316409794
      • 10: 316409794
      • 11: 316409794
      • 12: 316409794
      • 13: 316409794
      • 14: 316409794
      • 15: 316409794
      Backtrace
      • 14. app/Models/UserAccess/UserAccess.php:784
      • 15. middleware::check_user_access:114
      • 16. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Middleware/SubstituteBindings.php:50
      • 18. vendor/laravel/framework/src/Illuminate/Pipeline/Pipeline.php:183
    • SELECT at.type_name, p.copyright, p.publisher_location,m.month,y.year, a.publish_on, a.nid article_nid,a.article_id, a.pmid, a.issue_id, a.title, a.abstract,a.podcast,a.altmetric_score,a.altmetric_url,a.kudos_url, a.page_count, a.first_page, a.elocator, a.last_page, i.publication_date, a.file_name, a.file_path, a.doi, a.is_epub,a.epub_type, a.volume_id, a.is_uploaded, a.editor_choice, a.is_epub, j.image_file_name, a.article_no, a.art_type AS article_type, a.supplementary_filename,a.html_filename,a.prc_filename,a.epub_filename, a.graph_abs_lg_filename, a.graph_abs_sm_filename, a.oa_image_lg_filename, a.oa_image_sm_filename, j.journal_banner,a.animated_abstract,a.erratum_in,a.erratum_for, (CASE WHEN a.issue_id =0 THEN j.epub_price ELSE j.price END) AS sell_price, j.epub_price, j.nid AS jour_nid, j.title AS journal_title, j.issn, j.eissn,j.journal_id, j.subtitle AS jour_subtitle, v.volume_id,v.volume_name AS volume, v.year_id, i.title AS issue, i.month_id ,i.type issue_type, j.subtitle,j.formerly_title, ac.subtitle AS epub_title,a.crossmark_enabled,a.text_mining_urls,a.license_urls,a.created, a.receivedate, a.revisedate, a.acceptdate,js.js_title FROM article a LEFT JOIN article_section ac ON a.is_epub = ac.art_sec_id LEFT JOIN journal_section js ON a.js_id = js.js_id LEFT JOIN article_type at ON a.art_type = at.art_type_id LEFT JOIN issue i ON a.issue_id = i.issue_id LEFT JOIN month m ON m.id = i.month_id LEFT JOIN volume v ON v.volume_id = a.volume_id INNER JOIN year y ON y.id = v.year_id INNER JOIN journal j ON j.journal_id = a.journal_id INNER JOIN publisher p ON p.publisher_id = j.publisher_id WHERE a.article_id=127430
      720μsalphaeurekaselec_live_10_06_2022Article.php#408
      Backtrace
      • 11. app/Models/Article.php:408
      • 12. app/Http/Controllers/ArticleController.php:2515
      • 13. app/Http/Controllers/ArticleController.php:2035
      • 14. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 15. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select * from `journal` where `journal_id` = 48 limit 1
      810μsalphaeurekaselec_live_10_06_2022Journal.php#64
      Bindings
      • 0: 48
      Backtrace
      • 14. app/Models/Journal.php:64
      • 15. app/Http/Controllers/ArticleController.php:2516
      • 16. app/Http/Controllers/ArticleController.php:2035
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 18. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select count(*) as aggregate from (select j.nid as journal_nid,j.flyer_link,j.title ,j.issn,j.eissn,j.keyword, j.journal_id as journal_id, j.subtitle, j.image_file_name,j.description,j.journal_insight_url,j.doi from `subject_journal` as `sj` inner join `journal` as `j` on `j`.`journal_id` = `sj`.`journal_id` where j.journal_status=1 and subject_id IN (SELECT subject_id FROM subject_journal WHERE journal_id=48) and sj.journal_id!=48 group by `j`.`nid`) as `aggregate_table`
      630μsalphaeurekaselec_live_10_06_2022Subject.php#200
      Backtrace
      • 16. app/Models/Subject.php:200
      • 17. app/Http/Controllers/ArticleController.php:2517
      • 18. app/Http/Controllers/ArticleController.php:2035
      • 19. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 20. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select j.nid as journal_nid,j.flyer_link,j.title ,j.issn,j.eissn,j.keyword, j.journal_id as journal_id, j.subtitle, j.image_file_name,j.description,j.journal_insight_url,j.doi from `subject_journal` as `sj` inner join `journal` as `j` on `j`.`journal_id` = `sj`.`journal_id` where j.journal_status=1 and subject_id IN (SELECT subject_id FROM subject_journal WHERE journal_id=48) and sj.journal_id!=48 group by `j`.`nid` order by `j`.`journal_id` asc limit 10 offset 0
      530μsalphaeurekaselec_live_10_06_2022Subject.php#200
      Backtrace
      • 14. app/Models/Subject.php:200
      • 15. app/Http/Controllers/ArticleController.php:2517
      • 16. app/Http/Controllers/ArticleController.php:2035
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 18. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select count(*) as aggregate from (select v.nid as volume_id,e.nid,e.title,v.issn,v.eissn,v.isbn,v.eisbn,e.ebook_id, v.image_file_name,v.file_path,v.flyer_link,v.ebook_volume_id, v.volume_name,v.doi,v.year_id,v.introduction from `subject_ebook` as `se` inner join `ebook` as `e` on `e`.`ebook_id` = `se`.`ebook_id` inner join `ebook_volume` as `v` on `v`.`ebook_id` = `se`.`ebook_id` inner join `year` as `y` on `y`.`id` = `v`.`year_id` where subject_id IN (SELECT subject_id FROM subject_journal WHERE journal_id=48) and v.ebook_status='1' and y.year > 2020 group by `v`.`nid`) as `aggregate_table`
      780μsalphaeurekaselec_live_10_06_2022Subject.php#220
      Backtrace
      • 16. app/Models/Subject.php:220
      • 17. app/Http/Controllers/ArticleController.php:2518
      • 18. app/Http/Controllers/ArticleController.php:2035
      • 19. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 20. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select v.nid as volume_id,e.nid,e.title,v.issn,v.eissn,v.isbn,v.eisbn,e.ebook_id, v.image_file_name,v.file_path,v.flyer_link,v.ebook_volume_id, v.volume_name,v.doi,v.year_id,v.introduction from `subject_ebook` as `se` inner join `ebook` as `e` on `e`.`ebook_id` = `se`.`ebook_id` inner join `ebook_volume` as `v` on `v`.`ebook_id` = `se`.`ebook_id` inner join `year` as `y` on `y`.`id` = `v`.`year_id` where subject_id IN (SELECT subject_id FROM subject_journal WHERE journal_id=48) and v.ebook_status='1' and y.year > 2020 group by `v`.`nid` order by `v`.`ebook_volume_id` desc limit 10 offset 0
      750μsalphaeurekaselec_live_10_06_2022Subject.php#220
      Backtrace
      • 14. app/Models/Subject.php:220
      • 15. app/Http/Controllers/ArticleController.php:2518
      • 16. app/Http/Controllers/ArticleController.php:2035
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 18. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select * from `keywords` where `article_id` = '127430'
      220μsalphaeurekaselec_live_10_06_2022Keywords.php#43
      Bindings
      • 0: 127430
      Backtrace
      • 13. app/Models/Keywords.php:43
      • 14. app/Http/Controllers/ArticleController.php:2519
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select * from `article_citation` where `article_id` = '127430'
      2.76msalphaeurekaselec_live_10_06_2022Article.php#1570
      Bindings
      • 0: 127430
      Backtrace
      • 13. app/Models/Article.php:1570
      • 14. app/Http/Controllers/ArticleController.php:2520
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select CONCAT_WS(' ',au.first_name, ' ', ifnull(au.initials,''), ' ', au.last_name) as authors, CONCAT(au.last_name, IFNULL(CONCAT(' ', au.initials), ''), ' ', au.first_name) AS authorsRIS, CONCAT_WS(' ',au.last_name, ' ', ifnull(au.initials,''), ' ', au.first_name) as authorsCiteAs, CONCAT_WS(' ',au.first_name, IFNULL(CONCAT(' ', au.initials), ''), IFNULL(CONCAT(' ', au.last_name), '')) as authorsmodal , `au`.*, `af`.`ror_id`, `af`.`institution`, `af`.`department`, `af`.`country`, `af`.`city`, `af`.`address`, (GROUP_CONCAT(TRIM(BOTH ', ' FROM CONCAT(ifnull(concat(af.institution,','),''), ifnull(concat(af.department,','),''), ifnull(concat(af.address,','),''), ifnull(concat(af.city,','),''), ifnull(concat(af.country,','),''), ifnull(concat(af.postal_code,','),''), ifnull(concat(af.phone,','),''), ifnull(concat(af.fax,','),''))) SEPARATOR '|')) as `author_affiliation`, (GROUP_CONCAT(TRIM(BOTH ', ' FROM CONCAT(ifnull(concat(af.web_view,','),''))) SEPARATOR '|')) as `web_view` from `author` as `au` left join `author_affiliation` as `af` on `au`.`author_id` = `af`.`author_id` where `au`.`article_id` = '127430' group by `au`.`author_id` order by `au`.`article_id` asc, `au`.`sequence` asc
      1.96msalphaeurekaselec_live_10_06_2022Author.php#86
      Bindings
      • 0: 127430
      Backtrace
      • 13. app/Models/Author.php:86
      • 14. app/Http/Controllers/ArticleController.php:2533
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select `bo`.* from `bundle_offer` as `bo` where `bo`.`bundle_status` = 'A' order by `bo`.`bundle_id` desc
      260μsalphaeurekaselec_live_10_06_2022BundleOffer.php#57
      Bindings
      • 0: A
      Backtrace
      • 13. app/Models/BundleOffer.php:57
      • 14. app/Http/Controllers/ArticleController.php:2535
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select `subtitle` from `journal` where `continues_publication_journal` = 1
      500μsalphaeurekaselec_live_10_06_2022Article.php#1960
      Bindings
      • 0: 1
      Backtrace
      • 13. app/Models/Article.php:1960
      • 14. app/Http/Controllers/ArticleController.php:2062
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • Select j.subtitle, v.volume_id as volume_id,v.year_id,y.year as year,v.volume_name, v.total_no_of_issues, i.issue_id as issue_id,i.title as issue, i.publication_date as issue_pub_date from journal j join volume v on j.journal_id = v.journal_id join issue i on v.volume_id = i.volume_id join article a on a.issue_id = i.issue_id join year y on v.year_id = y.id where j.journal_id = 48 and i.is_uploaded = 1 order by v.volume_name+0 desc, i.title+0 desc limit 1
      38.51msalphaeurekaselec_live_10_06_2022Issue.php#298
      Backtrace
      • 11. app/Models/Issue.php:298
      • 12. app/Http/Controllers/ArticleController.php:2068
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select a.nid,a.publish_on, a.pmid,a.article_id,a.doi,j.journal_id,j.subtitle,v.volume_name,a.volume_id as volume_id, a.issue_id,a.title,first_page, last_page, page_count,abstract,ifnull(is_abstract,"y"),asec.title as article_section,at.type_name as article_type_name, a.article_id as ArticleID ,is_epub,epub_price,epub_type,a.created, y.year from `article` as `a` left join `article_section` as `asec` on `asec`.`art_sec_id` = `a`.`is_epub` left join `article_type` as `at` on `at`.`art_type_id` = `a`.`art_type` left join `journal` as `j` on `j`.`journal_id` = `a`.`journal_id` inner join `volume` as `v` on `a`.`volume_id` = `v`.`volume_id` inner join `year` as `y` on `v`.`year_id` = `y`.`id` where a.article_status != "W" and a.is_epub = 1 and a.journal_id = 48 and a.is_uploaded = 1 group by `a`.`article_id` order by `a`.`publish_on` desc
      22.99msalphaeurekaselec_live_10_06_2022Article.php#528
      Backtrace
      • 13. app/Models/Article.php:528
      • 14. app/Http/Controllers/ArticleController.php:2070
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select a.nid,a.publish_on, a.pmid,a.article_id,a.doi,j.journal_id,j.subtitle,v.volume_name,a.volume_id as volume_id, a.issue_id,a.title,first_page, last_page, page_count,abstract,ifnull(is_abstract,"y"),asec.title as article_section,at.type_name as article_type_name, a.article_id as ArticleID ,is_epub,epub_price,epub_type,a.created, y.year from `article` as `a` left join `article_section` as `asec` on `asec`.`art_sec_id` = `a`.`is_epub` left join `article_type` as `at` on `at`.`art_type_id` = `a`.`art_type` left join `journal` as `j` on `j`.`journal_id` = `a`.`journal_id` inner join `volume` as `v` on `a`.`volume_id` = `v`.`volume_id` inner join `year` as `y` on `v`.`year_id` = `y`.`id` where a.article_status != "W" and a.is_epub = 4 and a.journal_id = 48 and a.is_uploaded = 1 group by `a`.`article_id` order by `a`.`publish_on` desc
      19.74msalphaeurekaselec_live_10_06_2022Article.php#528
      Backtrace
      • 13. app/Models/Article.php:528
      • 14. app/Http/Controllers/ArticleController.php:2071
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select pdf, html, epub, prc from `article_metrics` where `article_id` = 127430 limit 1
      360μsalphaeurekaselec_live_10_06_2022Article.php#744
      Bindings
      • 0: 127430
      Backtrace
      • 14. app/Models/Article.php:744
      • 15. app/Http/Controllers/ArticleController.php:2091
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from content_by_diseases where content_id = 127430 and content_type = 'article' order by status desc limit 1
      380μsalphaeurekaselec_live_10_06_2022Article.php#751
      Backtrace
      • 11. app/Models/Article.php:751
      • 12. app/Http/Controllers/ArticleController.php:2094
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `node_meta` where `nid` = 210697 limit 1
      300μsalphaeurekaselec_live_10_06_2022Meta.php#30
      Bindings
      • 0: 210697
      Backtrace
      • 14. app/Models/Meta.php:30
      • 15. app/Http/Controllers/ArticleController.php:2101
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select `bo`.* from `bundle_offer` as `bo` where `bo`.`bundle_status` = 'A' order by `bo`.`bundle_id` desc
      320μsalphaeurekaselec_live_10_06_2022BundleOffer.php#57
      Bindings
      • 0: A
      Backtrace
      • 13. app/Models/BundleOffer.php:57
      • 14. app/Http/Controllers/ArticleController.php:2108
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `tbl_ht_submission` as `h` where `h`.`subtitle` = 'LOC' and (h.proposal_closing_date = 0 OR TO_DAYS(FROM_UNIXTIME(h.proposal_closing_date)) >= TO_DAYS(NOW())) order by `h`.`manuscript` asc
      290μsalphaeurekaselec_live_10_06_2022Article.php#2025
      Bindings
      • 0: LOC
      Backtrace
      • 13. app/Models/Article.php:2025
      • 14. app/Http/Controllers/ArticleController.php:2112
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select count(*) as total_count, content_type_access_id as access_type from journal_access where content_type_id = '127430' and content_type = 'a' and ( (from_date <= CURDATE() and to_date >= CURDATE() and perpetual= 0) or (from_date is null and to_date is null and perpetual= 1) )
      440μsalphaeurekaselec_live_10_06_2022ContentAccess.php#647
      Backtrace
      • 11. app/Models/ContentAccess.php:647
      • 12. app/Http/Controllers/ArticleController.php:2186
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select count(*) as total_count, content_type_access_id as access_type from journal_access where content_type_id = '12346' and content_type = 'i' and ( (from_date <= CURDATE() and to_date >= CURDATE() and perpetual= 0) or (from_date is null and to_date is null and perpetual= 1) )
      390μsalphaeurekaselec_live_10_06_2022ContentAccess.php#647
      Backtrace
      • 11. app/Models/ContentAccess.php:647
      • 12. app/Http/Controllers/ArticleController.php:2207
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select count(*) as total_count, content_type_access_id as access_type from journal_access where content_type_id = '3344' and content_type = 'v' and ( (from_date <= CURDATE() and to_date >= CURDATE() and perpetual= 0) or (from_date is null and to_date is null and perpetual= 1) )
      350μsalphaeurekaselec_live_10_06_2022ContentAccess.php#647
      Backtrace
      • 11. app/Models/ContentAccess.php:647
      • 12. app/Http/Controllers/ArticleController.php:2231
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Trial Access" as access_base_text, CASE j.type WHEN 111 THEN true ELSE false END as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"volume" as access_level,"" as issue_id,"" as article_id from `user_access_journal_volume_trail` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.volume_id = 3344) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Subscribed" as access_base_text, false as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"volume" as access_level,"" as issue_id,"" as article_id from `user_access_journal_volume_corporate` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.volume_id = 3344) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Token Based Access" as access_base_text, false as terms_popup, "R" as content_download_type, j.uc_id as restricted_user_access_key, "v" as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"volume" as access_level,"" as issue_id,"" as article_id from `user_access_journal_volume_token` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.volume_id = 3344)
      28.72msalphaeurekaselec_live_10_06_2022UserAccess.php#1266
      Backtrace
      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ArticleController.php:2272
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Trial Access" as access_base_text, CASE j.type WHEN 111 THEN true ELSE false END as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"issue" as access_level,j.issue_id,"" as article_id from `user_access_issue_trail` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.issue_id = 12346) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Subscribed" as access_base_text, false as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"issue" as access_level,j.issue_id,"" as article_id from `user_access_issue_corporate` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.issue_id = 12346) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Token Based Access" as access_base_text, false as terms_popup, "R" as content_download_type, j.uc_id as restricted_user_access_key, "v" as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"issue" as access_level,j.issue_id,"" as article_id from `user_access_issue_token` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.issue_id = 12346)
      880μsalphaeurekaselec_live_10_06_2022UserAccess.php#1266
      Backtrace
      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ArticleController.php:2297
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Trial Access" as access_base_text, CASE j.type WHEN 111 THEN true ELSE false END as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"article" as access_level, j.issue_id, j.article_id from `user_access_article_trail` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.article_id = 127430) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Subscribed" as access_base_text, false as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"article" as access_level, j.issue_id, j.article_id from `user_access_article_corporate` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.article_id = 127430) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Token Based Access" as access_base_text, false as terms_popup, "R" as content_download_type, j.uc_id as restricted_user_access_key, "v" as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"article" as access_level, j.issue_id, j.article_id from `user_access_article_token` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316409794 and j.to_ip >=316409794 )) and ((j.from_date <= 1740550638 and j.to_date >= 1740550638 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.article_id = 127430)
      940μsalphaeurekaselec_live_10_06_2022UserAccess.php#1266
      Backtrace
      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ArticleController.php:2329
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `article` where `first_page` < '370' and is_uploaded = 1 and issue_id = 12346 order by cast(first_page as SIGNED) desc limit 1
      900μsalphaeurekaselec_live_10_06_2022Article.php#1819
      Bindings
      • 0: 370
      Backtrace
      • 14. app/Models/Article.php:1819
      • 15. app/Http/Controllers/ArticleController.php:2470
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `article` where `last_page` > '375' and is_uploaded = 1 and issue_id = 12346 order by cast(first_page as SIGNED) asc limit 1
      640μsalphaeurekaselec_live_10_06_2022Article.php#1831
      Bindings
      • 0: 375
      Backtrace
      • 14. app/Models/Article.php:1831
      • 15. app/Http/Controllers/ArticleController.php:2472
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select `language_id` from `multilanguage` where `short_code` = 'en'
      250μsalphaeurekaselec_live_10_06_2022ArticleController.php#2497
      Bindings
      • 0: en
      Backtrace
      • 14. app/Http/Controllers/ArticleController.php:2497
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:206
    • select `source_lang_label`, `target_lang_label` from `multilanguage_labels` where `target_lang_id` = 1
      210μsalphaeurekaselec_live_10_06_2022MultiLanguage.php#23
      Bindings
      • 0: 1
      Backtrace
      • 13. app/Models/MultiLanguage.php:23
      • 14. app/Http/Controllers/ArticleController.php:2498
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select `id` from `multilanguage_article` where `article_id` = 127430 limit 1
      3.47msalphaeurekaselec_live_10_06_2022ArticleController.php#2506
      Bindings
      • 0: 127430
      Backtrace
      • 16. app/Http/Controllers/ArticleController.php:2506
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 18. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 19. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
      • 20. vendor/laravel/framework/src/Illuminate/Routing/Route.php:206
    • select b.banner_link, b.banner_name, b.banner_script, b.banner_remarks, b.banner_file_name, b.banner_placement, bd.content_type, bd.content_id from `tbl_banner` as `b` inner join `tbl_banner_detail` as `bd` on `bd`.`banner_id` = `b`.`banner_id` inner join `users` as `u` on `u`.`id` = `b`.`updated_by` inner join `journal` as `j` on `j`.`journal_id` = `bd`.`content_id` where `b`.`banner_journal` = 1 and `bd`.`content_type` = 'J' and `bd`.`content_id` = 48 and `b`.`banner_from_date` <= 1740550638 and `b`.`banner_to_date` >= 1740550638 and `b`.`banner_status` = 'A' order by `b`.`banner_id` desc
      1.17msalphaeurekaselec_live_10_06_2022Banner.php#95
      Bindings
      • 0: 1
      • 1: J
      • 2: 48
      • 3: 1740550638
      • 4: 1740550638
      • 5: A
      Backtrace
      • 13. app/Models/Banner.php:95
      • 14. app/Http/helpers.php:404
      • 17. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 18. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
    • select b.banner_link, b.banner_name, b.banner_script, b.banner_remarks, b.banner_file_name, b.banner_placement, bd.content_type, bd.content_id from `tbl_banner` as `b` inner join `tbl_banner_detail` as `bd` on `bd`.`banner_id` = `b`.`banner_id` inner join `users` as `u` on `u`.`id` = `b`.`updated_by` inner join `journal` as `j` on `j`.`journal_id` = `bd`.`content_id` where `b`.`banner_journal` = 1 and `bd`.`content_type` = 'J' and `bd`.`content_id` = 48 and `b`.`banner_from_date` <= 1740550638 and `b`.`banner_to_date` >= 1740550638 and `b`.`banner_status` = 'A' order by `b`.`banner_id` desc
      1.18msalphaeurekaselec_live_10_06_2022Banner.php#95
      Bindings
      • 0: 1
      • 1: J
      • 2: 48
      • 3: 1740550638
      • 4: 1740550638
      • 5: A
      Backtrace
      • 13. app/Models/Banner.php:95
      • 14. app/Http/helpers.php:404
      • 17. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 18. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
    • select count(*) as aggregate from `uc_cart_products` where cart_id='c5a51c1d7bae6340da34bb2bb1067ec2'
      240μsalphaeurekaselec_live_10_06_2022Cart.php#271
      Backtrace
      • 15. app/Models/Cart.php:271
      • 16. view::layouts._header:260
      • 18. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 20. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
    App\Models\MultiLanguage
    1MultiLanguage.php#?
        _token
        UuUNYNnSK9fAieqi97vdVu2b849OCvqJWFH757XN
        uc_cart_id
        c5a51c1d7bae6340da34bb2bb1067ec2
        _previous
        array:1 [ "url" => "http://alpha.eurekaselect.com/article/127430" ]
        _flash
        array:2 [ "old" => [] "new" => [] ]
        PHPDEBUGBAR_STACK_DATA
        []
        path_info
        /article/127430
        status_code
        200
        
        status_text
        OK
        format
        html
        content_type
        text/html; charset=UTF-8
        request_query
        []
        
        request_request
        []
        
        request_headers
        0 of 0
        array:9 [ "cookie" => array:1 [ 0 => "wayfindertarget=eyJpdiI6InZUSGJEVUNVcHEvUzUyaGVrRVFzYlE9PSIsInZhbHVlIjoiWE1OWjNIT2lTd3d3U0VKODBsVk9INW1JdzNBVitubDR0c0FNYk1QQ1R6Yz0iLCJtYWMiOiJhMTBlM2VkMDM3OWJhNTY1MDQ3ZTJhNDdlNzRjNmM0ZDRhOTc0YjZjNGRiYzlkNzkwNTZjZDljYzc0YTUyZGVmIiwidGFnIjoiIn0%3Dwayfindertarget=eyJpdiI6InZUSGJEVUNVcHEvUzUyaGVrRVFzYlE9PSIsInZhbHVlIjoiWE1OWjNIT2lTd3d3U0VKODBsVk9INW1JdzNBVitubDR0c0FNYk1QQ1R6Yz0iLCJtYWMiOiJhMTBlM2VkMDM3OWJh" ] "accept-encoding" => array:1 [ 0 => "gzip, deflate" ] "accept" => array:1 [ 0 => "text/html,application/xhtml+xml,application/xml;q=0.9,image/avif,image/webp,image/apng,*/*;q=0.8,application/signed-exchange;v=b3;q=0.7" ] "user-agent" => array:1 [ 0 => "Mozilla/5.0 AppleWebKit/537.36 (KHTML, like Gecko; compatible; ClaudeBot/1.0; +claudebot@anthropic.com)" ] "upgrade-insecure-requests" => array:1 [ 0 => "1" ] "cache-control" => array:1 [ 0 => "no-cache" ] "pragma" => array:1 [ 0 => "no-cache" ] "connection" => array:1 [ 0 => "keep-alive" ] "host" => array:1 [ 0 => "alpha.eurekaselect.com" ] ]
        request_cookies
        0 of 0
        array:1 [ "wayfindertarget" => null ]
        response_headers
        0 of 0
        array:5 [ "content-type" => array:1 [ 0 => "text/html; charset=UTF-8" ] "cache-control" => array:1 [ 0 => "no-cache, private" ] "date" => array:1 [ 0 => "Wed, 26 Feb 2025 06:17:18 GMT" ] "set-cookie" => array:2 [ 0 => "XSRF-TOKEN=eyJpdiI6ImNhczJONTNLMVY2RXpWN3F0SmdFU3c9PSIsInZhbHVlIjoiZktINWFMNGZ4NGhJdU51NUdBR3U0K0luMTg2bzU3eXJWeDQ1d0xVZFp6QjMyVmtIVzJYTlhvbGFKWURtcmhLTkdTUVRHMU1KY1RyY0IxcFBmam93N2lGSHZJYnNDV1hOakRhcFI3eFlxWWpIV1VnemIzVmJDUlN4MW9JcDZyZmUiLCJtYWMiOiJlMGYzMDczMzc2NjAxY2QyYzQyNGNmZGIzMmYzNGEzNGRkNjk2ODQ0OTZlYmE0OTkwMTg1YmIzMDhhN2ZhZTMwIiwidGFnIjoiIn0%3D; expires=Fri, 28 Feb 2025 18:17:18 GMT; Max-Age=216000; path=/; secure; samesite=laxXSRF-TOKEN=eyJpdiI6ImNhczJONTNLMVY2RXpWN3F0SmdFU3c9PSIsInZhbHVlIjoiZktINWFMNGZ4NGhJdU51NUdBR3U0K0luMTg2bzU3eXJWeDQ1d0xVZFp6QjMyVmtIVzJYTlhvbGFKWURtcmhLTkdTUVRHM" 1 => "alphaeurekaselectnet_session=eyJpdiI6IkNXRnpZS2tFdUFHOUVTUWthU1FoSHc9PSIsInZhbHVlIjoiaG9NS3ZaejJNcTVSemh0MFZWUGZkdk1EaVVJWXZmS1BaR09JWVpmT2pQMDRYY1k5NEdBeTJlM1grTmVXTjJMOEI1Skh3cjZlemhZbjBwRW95REV3d09aZVhaYURiYnJ1UFoxbGE4WnJlTHRybnBzS2NOOHJtd0hjNm5FSnppUnkiLCJtYWMiOiJhYWZhMDRmYzUzZmE2YWY1MDRkZmFjYWNhNGY0NjhkOWYwYzE1NDVkNWNhNzQ4ZjU1ODFiYmVkODdlNDI4ZWNhIiwidGFnIjoiIn0%3D; path=/; secure; httponly; samesite=laxalphaeurekaselectnet_session=eyJpdiI6IkNXRnpZS2tFdUFHOUVTUWthU1FoSHc9PSIsInZhbHVlIjoiaG9NS3ZaejJNcTVSemh0MFZWUGZkdk1EaVVJWXZmS1BaR09JWVpmT2pQMDRYY1k5NEdBeTJlM1g" ] "Set-Cookie" => array:2 [ 0 => "XSRF-TOKEN=eyJpdiI6ImNhczJONTNLMVY2RXpWN3F0SmdFU3c9PSIsInZhbHVlIjoiZktINWFMNGZ4NGhJdU51NUdBR3U0K0luMTg2bzU3eXJWeDQ1d0xVZFp6QjMyVmtIVzJYTlhvbGFKWURtcmhLTkdTUVRHMU1KY1RyY0IxcFBmam93N2lGSHZJYnNDV1hOakRhcFI3eFlxWWpIV1VnemIzVmJDUlN4MW9JcDZyZmUiLCJtYWMiOiJlMGYzMDczMzc2NjAxY2QyYzQyNGNmZGIzMmYzNGEzNGRkNjk2ODQ0OTZlYmE0OTkwMTg1YmIzMDhhN2ZhZTMwIiwidGFnIjoiIn0%3D; expires=Fri, 28-Feb-2025 18:17:18 GMT; path=/; secureXSRF-TOKEN=eyJpdiI6ImNhczJONTNLMVY2RXpWN3F0SmdFU3c9PSIsInZhbHVlIjoiZktINWFMNGZ4NGhJdU51NUdBR3U0K0luMTg2bzU3eXJWeDQ1d0xVZFp6QjMyVmtIVzJYTlhvbGFKWURtcmhLTkdTUVRHM" 1 => "alphaeurekaselectnet_session=eyJpdiI6IkNXRnpZS2tFdUFHOUVTUWthU1FoSHc9PSIsInZhbHVlIjoiaG9NS3ZaejJNcTVSemh0MFZWUGZkdk1EaVVJWXZmS1BaR09JWVpmT2pQMDRYY1k5NEdBeTJlM1grTmVXTjJMOEI1Skh3cjZlemhZbjBwRW95REV3d09aZVhaYURiYnJ1UFoxbGE4WnJlTHRybnBzS2NOOHJtd0hjNm5FSnppUnkiLCJtYWMiOiJhYWZhMDRmYzUzZmE2YWY1MDRkZmFjYWNhNGY0NjhkOWYwYzE1NDVkNWNhNzQ4ZjU1ODFiYmVkODdlNDI4ZWNhIiwidGFnIjoiIn0%3D; path=/; secure; httponlyalphaeurekaselectnet_session=eyJpdiI6IkNXRnpZS2tFdUFHOUVTUWthU1FoSHc9PSIsInZhbHVlIjoiaG9NS3ZaejJNcTVSemh0MFZWUGZkdk1EaVVJWXZmS1BaR09JWVpmT2pQMDRYY1k5NEdBeTJlM1g" ] ]
        session_attributes
        0 of 0
        array:5 [ "_token" => "UuUNYNnSK9fAieqi97vdVu2b849OCvqJWFH757XN" "uc_cart_id" => "c5a51c1d7bae6340da34bb2bb1067ec2" "_previous" => array:1 [ "url" => "http://alpha.eurekaselect.com/article/127430" ] "_flash" => array:2 [ "old" => [] "new" => [] ] "PHPDEBUGBAR_STACK_DATA" => [] ]
        ClearShow all
        Date ↕MethodURLData
        #12025-02-26 06:17:18GET/article/127430414361