Abstract
This review presents developments in the young field of dehydrogenative coupling reactions of phosphines. Catalytic phosphorus – element bond formation via dehydrocoupling has rapidly expanded since the first discoveries in the mid 1990s. A survey of the available catalysts, P – P and P – E products, and mechanistic understanding is presented with emphasis on the emerging synthetic applications of this reaction.
Keywords: dehydrogenative, phosphines, Catalytic phosphorus, –, element, dehydrocoupling, catalysts
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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