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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Letter Article

Magnetically Recyclable Silica-Coated Magnetite-Molybdate Nanocatalyst and its Applications in N-Formylation Reactions Under Solvent-Free Conditions

Author(s): Runjhun Tandon, Shripad Patil*, Nitin Tandon* and Pushpendra Kumar

Volume 19, Issue 8, 2022

Published on: 12 January, 2022

Page: [616 - 626] Pages: 11

DOI: 10.2174/1570178619666220112112901

Price: $65

Abstract

A novel magnetite silica-coated nanoparticle-supported molybdate nanocatalyst has been prepared successfully by a simple co-precipitation method. Prepared nanocatalyst has been characterized by different techniques like Fourier Transmission Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), Field Emission Scanning Electron Microscope (FE-SEM), and Energy Dispersive X-ray Spectroscopy (EDX). Further, the catalytic activity of the nanocatalyst was explored for N-formylation reactions under solvent-free conditions. Interestingly, the catalyst could be reused for 10 cycles, and only 2 mol % of the catalyst was sufficient to catalyze the N-formylation reaction at 70°C under solvent-free conditions.

Keywords: Magnetic nanoparticles, N-formylation, catalytic activity, green chemistry, formamide derivatives, nanocatalyst.

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