Abstract
The metal-mediated formation of heterocycles is one of the most emerging and important strategies in organic chemistry. The reactions utilized previously for the synthesis of heterocycles were less familiar to the scientists due to their complicated work-up, expensive nature, and difficult operations. The silver-assisted cyclic reactions are highly efficient for both regioselective and stereoselective syntheses of five-membered fused N-heterocyclic compounds. The applications of silver in the preparation of five-membered fused N-heterocyclic compounds are covered in this review article.
Keywords: Silver, catalysis, heterocycles, nitrogen, synthesis, five-membered heterocycles.
Graphical Abstract
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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