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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Letter Article

Synthesis, Characterization and Application of N,N-Dimethyl-NSulfoethan Ammonium tetra-Chloro Aluminate: A Novel micro-Heterogeneous Catalyst for Synthesis of tri-Arylmethanes

Author(s): Saeid Azimi* and Niloofar Mohamadighader

Volume 18, Issue 8, 2021

Published on: 25 September, 2020

Page: [594 - 603] Pages: 10

DOI: 10.2174/1570178617999200925205313

Price: $65

Abstract

A new solid catalyst was synthesized from an ionic liquid and heterogenised by changing the anion reaction. The new heterogeneous acidic catalyst was characterized by SEM images, EDS analysis, AFM images, Ft-IR, HNMR, 13CNMR and Mass Spectroscopy. It was applied to the synthesis of tri-arylmethanes throughout one-pot tri-component reactions among aromatic aldehydes, N,N-dimethylaniline and other carbonic nucleophiles such as anisole and indole. Hence, the synthesis of convenient and inexpensive micro-heterogeneous catalyst was introduced, the efficiency of which was confirmed. Also, various useful products were synthesized throughout this simple and clean procedure.

Keywords: Micro-heterogeneous catalyst, Ionic liquid, N, N-Dimethyl-N-Sulfoethan Ammonium tetra-Chloro Aluminate, Triarylmethanes.

Graphical Abstract


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