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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Research Article

Solid State Kinetics and Antimicrobial Studies for Copper (II) Sesame and Copper (II) Groundnut Complexes with Substituted Benzothiazole Ligand

Author(s): Asha Meena*, Vandana Sukhadia and Rashmi Sharma

Volume 18, Issue 6, 2021

Published on: 12 August, 2020

Page: [477 - 489] Pages: 13

DOI: 10.2174/1570178617999200812134745

Price: $65

Abstract

The aim of this manuscript is to give an overview of new findings in the field of thermal degradation and antimicrobial studies for copper (II) sesame and copper (II) groundnut complexes with substituted benzothiazole ligand. Solid state kinetics and thermal degradation have gained the attention of the scientific community not only due to their numerous applications in environment, energy, wastewater treatment, pollution control and green chemistry but also due to their wide range of biological activities. This work aims to explore the study of chemical steps of the investigated degradation and the evaluation of the kinetic and thermodynamic parameters of the newly synthesized biologically active complexes (CSBe and CGBe) derived from two different edible oils, i.e., sesame and groundnut and ligand containing nitrogen, oxygen and sulphur atoms, i.e., 2-amino-6-ethoxy benzothiazole. The studies include Coats-Redfern equation (CRE), Horowitz-Metzger equation (HME), Broido equation (BE) and Piloyan-Novikova equation (PNE) for the analysis of the degradation and energetics for each step using kinetic data. The observation suggests that CGBe takes a longer time and higher temperature to decompose completely than CSBe. Antimicrobial activities against Staphylococcus aureus of these compounds have also been analysed which may provide an important account of information about their industrial utilization. The TGA study reveals that CSBe and CGBe complexes undergo stepwise thermal degradation of the ligand-soap bond of complex and saturated and unsaturated fatty acid components of edible oils, i.e., sesame and groundnut. The order of antimicrobial activities of the two complexes studied is – CSBe > CGBe. These results reveal that the nature of different nitrogen, oxygen and sulphur containing ligands coordinated with copper ion plays a significant role in the inhibition activity.

Keywords: Thermal degradation, kinetic parameters, thermodynamic parameters, edible oils, antimicrobial activities.

Graphical Abstract

[1]
Balkose, D.; Egbuchunam, T.O.; Okieimen, F.E. J. Therm. Anal. Calorim., 2010, 101, 795-799.
[http://dx.doi.org/10.1007/s10973-010-0940-4]
[2]
Ribeiro, S.A.O.; Nicacio, A.E. Food Sci. Technol. (Campinas), 2016, 65, 464-470.
[http://dx.doi.org/10.1016/j.lwt.2015.08.053]
[3]
Gharby, S.; Charrouf, Z. J. Saudi Soc. Agric. Sci., 2017, 16, 105-111.
[http://dx.doi.org/10.1016/j.jssas.2015.03.004]
[4]
Denniston, K.J.; Topping, J.J.; Cariet, R.L. General Organic and Biochemistry, 4th ed; McGraw Hill Companies: New York, 2004, p. 432.
[5]
Tank, P.; Sharma, R.; Sharma, A. Curr. Phys. Chem., 2018, 8(1), 46-57.
[http://dx.doi.org/10.2174/1877946808666180102152443]
[6]
Khan, S.; Sharma, R.; Sharma, A.K. 15 K. Curr. Phy. Chem., 2018, 8(1), 46-57.
[http://dx.doi.org/10.2174/1877946808666180102152443]
[7]
Mehrotra, K.N.; Varma, R.P. J. Am. Chem. Soc., 1969, 46, 152-154.
[http://dx.doi.org/10.1007/BF02635721]
[8]
Mehrotra, K.N.; Chauhan, M.; Shukla, R.K. J. Am. Oil Chem. Soc., 1990, 67, 446-450.
[http://dx.doi.org/10.1007/BF02638959]
[9]
Sharma, A.K.; Sharma, R.; Gangwal, A. Open Pharm. Sci. J., 2018, 5, 1-11.
[http://dx.doi.org/10.2174/1874844901805010001]
[10]
Akhtar, Y. Fluid Phase Equilib., 2007, 258(2), 125-130.
[http://dx.doi.org/10.1016/j.fluid.2007.01.043]
[11]
Bhati, S.K.; Kumar, A. Eur. J. Med. Chem., 2008, 43(11), 2323-2330.
[http://dx.doi.org/10.1016/j.ejmech.2007.10.012] [PMID: 18063224]
[12]
Sharma, R.; Sharma, A.K. Biomed J Sci. & Tech Res., 2017, 1(5) BJSTR.MS.ID.000441.
[http://dx.doi.org/10.26717/BJSTR.2017.01.000441]
[13]
Rosen, M.J. Surfactants and Interfacial Phenomena, 2nd ed; Wiley Interscience: New York, 1989.
[14]
Swisher, R.D. Surfactant biodegradation; M; Dekker: New York, 1970.
[15]
Karthikeyan, S.; Ranjith, P. Industrial Pollution Control, 2007, 23, 37-42.
[16]
Sharma, R.; Saxena, M.; Sharma, N. Int. J. Chem. Sci., 2012, 10, 143-149.
[http://dx.doi.org/10.19080/GJPPS.2017.03.555619]
[17]
Raman, N.; Joseph, J.; Velan, A.S.; Pothiraj, C. Mycobiology, 2006, 34(4), 214-218.
[http://dx.doi.org/10.4489/MYCO.2006.34.4.214] [PMID: 24039502]
[18]
Borhade, S.S. Int. J. Pharm. & Life Sci., 2012, 3, 1344-1350.
[19]
Angelusiu, M.V.; Almajan, G.L.; Ilies, D.C.; Rosu, T.; Negoiu, M. Chem. Bull. Politehnica Univ., (Timisoara); , 2008, 53, pp. (67)1-2.
[20]
Mahajan, K.; Swami, M.; Singh, R.V. Russ. J. Coord. Chem., 2009, 35, 179-185.
[http://dx.doi.org/10.1134/S1070328409030038]
[21]
Garg, B.S.; Nandan Kumar, D.; Singh, R.V. Spectrochim. Acta A Mol. Biomol. Spectrosc., 2003, 59(2), 229-234.
[http://dx.doi.org/10.1016/S1386-1425(02)00142-7] [PMID: 12685895]
[22]
Joram, A.; Sharma, R.; Sharma, A.K. Open chem. J., 2018, 5, 145-157.
[http://dx.doi.org/10.2174/1874842201805010145]
[23]
Riddick, J.R.; Bunger, W.B. Organic solvents: Physical properties and methods of purification; Wiley Interscience: New York, 1970.
[24]
Sukhadia, V.; Sharma, R.; Meena, A. Curr. Phys. Chem., 2020, 10, 1-14.
[http://dx.doi.org/10.2174/1877946810666200221122053]
[25]
Meena, A.; Sharma, R. Journal of Applicable Chemistry, 2018, 7(6), 1703-1712.
[26]
Sharma, A.K.; Saxena, M.; Sharma, R. Open Chem. J., 2018, 5, 59-105.
[http://dx.doi.org/10.2174/1874842201805010089]
[27]
Adams, R. Organic reactions, John Wiley and sons: New York. 1959, 3, 240.
[28]
Meena, A.; Sharma, R.; Sukhadia, V. Curr. Phys. Chem., 2020, 10, 1-16.
[http://dx.doi.org/10.2174/1877946810666200116091321]
[29]
David, M.Z.; Daum, R.S. Clin. Microbiol. Rev., 2010, 23(3), 616-687.
[http://dx.doi.org/10.1128/CMR.00081-09] [PMID: 20610826]
[30]
Ito, T.; Katayama, Y.; Asada, K.; Mori, N.; Tsutsumimoto, K.; Tiensasitorn, C.; Hiramatsu, K. Antimicrob. Agents Chemother., 2001, 45(5), 1323-1336.
[http://dx.doi.org/10.1128/AAC.45.5.1323-1336.2001] [PMID: 11302791]
[31]
Jansen, W.T.; Beitsma, M.M.; Koeman, C.J.; van Wamel, W.J.; Verhoef, J.; Fluit, A.C. Antimicrob. Agents Chemother., 2006, 50(6), 2072-2078.
[http://dx.doi.org/10.1128/AAC.01539-05] [PMID: 16723568]
[32]
Valle, D.L., Jr; Andrade, J.I.; Puzon, J.J.M.; Cabrera, E.C.; Rivera, W.L. Asian Pac. J. Trop. Biomed., 2015, 5, 532-540.
[http://dx.doi.org/10.1016/j.apjtb.2015.04.005]
[33]
Anderson, D.A.; Freeman, E.S. J. Polym. Sci., Polym. Phys. Ed., 1961, 54(159), 253-260.
[http://dx.doi.org/10.1002/pol.1961.1205415920]
[34]
Doyle, C.D. Anal. Chern., 1961, 33(1), 77-79.
[http://dx.doi.org/10.1021/ac60169a022]
[35]
Doyle, C.D. J. Appl. Polym. Sci., 1961, 5(15), 285-292.
[http://dx.doi.org/10.1002/app.1961.070051506]
[36]
Coats, A.W.; Redfern, J.P. Nature, 1964, 201, 68-69.
[http://dx.doi.org/10.1038/201068a0]
[37]
Broido, A. J. Polymer Sci., Part B-2, 1969, 7(10), 1761-1773.
[http://dx.doi.org/10.1002/pol.1969.160071012]
[38]
Horowitz, H.H.; Metzger, A.G. Anal. Chem., 1963, 35(10), 1464-1468.
[http://dx.doi.org/10.1021/ac60203a013]
[39]
Piloyan, G.O.; Pyabchikov, I.D.; Novikova, I.S. Nature, 1966, 212, 1229.
[http://dx.doi.org/10.1038/2121229a0]
[40]
Salama, N.N.; Mohammad, M.A.; Fattah, T.A. J. Therm. Anal. Calorim., 2015, 120, 953-958.
[http://dx.doi.org/10.1007/s10973-015-4419-1]
[41]
Karapmar, E.; Gubbuk, I.H.; Taner, B.; Deveci, P.; Ozcan, E. J. Chem., 2013, 548067.
[http://dx.doi.org/10.1155/2013/548067]
[42]
Kumawat, P.; Sharma, R.; Sharma, A. Int. J. Environ. Anal. Chem., 2019, 99.
[http://dx.doi.org/10.1080/03067319.2019.1651302]
[43]
Atlas, R.M.; Snyder, J.W. CRC Press., 2014, 324
[44]
Shrivastava, G.; Shrivastava, M.; Shrivastava, G. Pharma. Tutor., 2018, 6, 1-5.
[http://dx.doi.org/10.29161/PT.v6.i9.2018.1]

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      6.79msalphaeurekaselec_live_10_06_2022Subject.php#220
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      • 16. app/Models/Subject.php:220
      • 17. app/Http/Controllers/ArticleController.php:2518
      • 18. app/Http/Controllers/ArticleController.php:2035
      • 19. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 20. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select v.nid as volume_id,e.nid,e.title,v.issn,v.eissn,v.isbn,v.eisbn,e.ebook_id, v.image_file_name,v.file_path,v.flyer_link,v.ebook_volume_id, v.volume_name,v.doi,v.year_id,v.introduction from `subject_ebook` as `se` inner join `ebook` as `e` on `e`.`ebook_id` = `se`.`ebook_id` inner join `ebook_volume` as `v` on `v`.`ebook_id` = `se`.`ebook_id` inner join `year` as `y` on `y`.`id` = `v`.`year_id` where subject_id IN (SELECT subject_id FROM subject_journal WHERE journal_id=48) and v.ebook_status='1' and y.year > 2020 group by `v`.`nid` order by `v`.`ebook_volume_id` desc limit 10 offset 0
      1.14msalphaeurekaselec_live_10_06_2022Subject.php#220
      Backtrace
      • 14. app/Models/Subject.php:220
      • 15. app/Http/Controllers/ArticleController.php:2518
      • 16. app/Http/Controllers/ArticleController.php:2035
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 18. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select * from `keywords` where `article_id` = '109063'
      19.89msalphaeurekaselec_live_10_06_2022Keywords.php#43
      Bindings
      • 0: 109063
      Backtrace
      • 13. app/Models/Keywords.php:43
      • 14. app/Http/Controllers/ArticleController.php:2519
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select * from `article_citation` where `article_id` = '109063'
      10.41msalphaeurekaselec_live_10_06_2022Article.php#1570
      Bindings
      • 0: 109063
      Backtrace
      • 13. app/Models/Article.php:1570
      • 14. app/Http/Controllers/ArticleController.php:2520
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select CONCAT_WS(' ',au.first_name, ' ', ifnull(au.initials,''), ' ', au.last_name) as authors, CONCAT(au.last_name, IFNULL(CONCAT(' ', au.initials), ''), ' ', au.first_name) AS authorsRIS, CONCAT_WS(' ',au.last_name, ' ', ifnull(au.initials,''), ' ', au.first_name) as authorsCiteAs, CONCAT_WS(' ',au.first_name, IFNULL(CONCAT(' ', au.initials), ''), IFNULL(CONCAT(' ', au.last_name), '')) as authorsmodal , `au`.*, `af`.`ror_id`, `af`.`institution`, `af`.`department`, `af`.`country`, `af`.`city`, `af`.`address`, (GROUP_CONCAT(TRIM(BOTH ', ' FROM CONCAT(ifnull(concat(af.institution,','),''), ifnull(concat(af.department,','),''), ifnull(concat(af.address,','),''), ifnull(concat(af.city,','),''), ifnull(concat(af.country,','),''), ifnull(concat(af.postal_code,','),''), ifnull(concat(af.phone,','),''), ifnull(concat(af.fax,','),''))) SEPARATOR '|')) as `author_affiliation`, (GROUP_CONCAT(TRIM(BOTH ', ' FROM CONCAT(ifnull(concat(af.web_view,','),''))) SEPARATOR '|')) as `web_view` from `author` as `au` left join `author_affiliation` as `af` on `au`.`author_id` = `af`.`author_id` where `au`.`article_id` = '109063' group by `au`.`author_id` order by `au`.`article_id` asc, `au`.`sequence` asc
      5.4msalphaeurekaselec_live_10_06_2022Author.php#86
      Bindings
      • 0: 109063
      Backtrace
      • 13. app/Models/Author.php:86
      • 14. app/Http/Controllers/ArticleController.php:2533
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select `bo`.* from `bundle_offer` as `bo` where `bo`.`bundle_status` = 'A' order by `bo`.`bundle_id` desc
      350μsalphaeurekaselec_live_10_06_2022BundleOffer.php#57
      Bindings
      • 0: A
      Backtrace
      • 13. app/Models/BundleOffer.php:57
      • 14. app/Http/Controllers/ArticleController.php:2535
      • 15. app/Http/Controllers/ArticleController.php:2035
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
    • select `subtitle` from `journal` where `continues_publication_journal` = 1
      790μsalphaeurekaselec_live_10_06_2022Article.php#1960
      Bindings
      • 0: 1
      Backtrace
      • 13. app/Models/Article.php:1960
      • 14. app/Http/Controllers/ArticleController.php:2062
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • Select j.subtitle, v.volume_id as volume_id,v.year_id,y.year as year,v.volume_name, v.total_no_of_issues, i.issue_id as issue_id,i.title as issue, i.publication_date as issue_pub_date from journal j join volume v on j.journal_id = v.journal_id join issue i on v.volume_id = i.volume_id join article a on a.issue_id = i.issue_id join year y on v.year_id = y.id where j.journal_id = 48 and i.is_uploaded = 1 order by v.volume_name+0 desc, i.title+0 desc limit 1
      113msalphaeurekaselec_live_10_06_2022Issue.php#298
      Backtrace
      • 11. app/Models/Issue.php:298
      • 12. app/Http/Controllers/ArticleController.php:2068
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select a.nid,a.publish_on, a.pmid,a.article_id,a.doi,j.journal_id,j.subtitle,v.volume_name,a.volume_id as volume_id, a.issue_id,a.title,first_page, last_page, page_count,abstract,ifnull(is_abstract,"y"),asec.title as article_section,at.type_name as article_type_name, a.article_id as ArticleID ,is_epub,epub_price,epub_type,a.created, y.year from `article` as `a` left join `article_section` as `asec` on `asec`.`art_sec_id` = `a`.`is_epub` left join `article_type` as `at` on `at`.`art_type_id` = `a`.`art_type` left join `journal` as `j` on `j`.`journal_id` = `a`.`journal_id` inner join `volume` as `v` on `a`.`volume_id` = `v`.`volume_id` inner join `year` as `y` on `v`.`year_id` = `y`.`id` where a.article_status != "W" and a.is_epub = 1 and a.journal_id = 48 and a.is_uploaded = 1 group by `a`.`article_id` order by `a`.`publish_on` desc
      64.1msalphaeurekaselec_live_10_06_2022Article.php#528
      Backtrace
      • 13. app/Models/Article.php:528
      • 14. app/Http/Controllers/ArticleController.php:2070
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select a.nid,a.publish_on, a.pmid,a.article_id,a.doi,j.journal_id,j.subtitle,v.volume_name,a.volume_id as volume_id, a.issue_id,a.title,first_page, last_page, page_count,abstract,ifnull(is_abstract,"y"),asec.title as article_section,at.type_name as article_type_name, a.article_id as ArticleID ,is_epub,epub_price,epub_type,a.created, y.year from `article` as `a` left join `article_section` as `asec` on `asec`.`art_sec_id` = `a`.`is_epub` left join `article_type` as `at` on `at`.`art_type_id` = `a`.`art_type` left join `journal` as `j` on `j`.`journal_id` = `a`.`journal_id` inner join `volume` as `v` on `a`.`volume_id` = `v`.`volume_id` inner join `year` as `y` on `v`.`year_id` = `y`.`id` where a.article_status != "W" and a.is_epub = 4 and a.journal_id = 48 and a.is_uploaded = 1 group by `a`.`article_id` order by `a`.`publish_on` desc
      47.57msalphaeurekaselec_live_10_06_2022Article.php#528
      Backtrace
      • 13. app/Models/Article.php:528
      • 14. app/Http/Controllers/ArticleController.php:2071
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select pdf, html, epub, prc from `article_metrics` where `article_id` = 109063 limit 1
      9.03msalphaeurekaselec_live_10_06_2022Article.php#744
      Bindings
      • 0: 109063
      Backtrace
      • 14. app/Models/Article.php:744
      • 15. app/Http/Controllers/ArticleController.php:2091
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from content_by_diseases where content_id = 109063 and content_type = 'article' order by status desc limit 1
      720μsalphaeurekaselec_live_10_06_2022Article.php#751
      Backtrace
      • 11. app/Models/Article.php:751
      • 12. app/Http/Controllers/ArticleController.php:2094
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `node_meta` where `nid` = 184805 limit 1
      6.5msalphaeurekaselec_live_10_06_2022Meta.php#30
      Bindings
      • 0: 184805
      Backtrace
      • 14. app/Models/Meta.php:30
      • 15. app/Http/Controllers/ArticleController.php:2101
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select `bo`.* from `bundle_offer` as `bo` where `bo`.`bundle_status` = 'A' order by `bo`.`bundle_id` desc
      580μsalphaeurekaselec_live_10_06_2022BundleOffer.php#57
      Bindings
      • 0: A
      Backtrace
      • 13. app/Models/BundleOffer.php:57
      • 14. app/Http/Controllers/ArticleController.php:2108
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `tbl_ht_submission` as `h` where `h`.`subtitle` = 'LOC' and (h.proposal_closing_date = 0 OR TO_DAYS(FROM_UNIXTIME(h.proposal_closing_date)) >= TO_DAYS(NOW())) order by `h`.`manuscript` asc
      570μsalphaeurekaselec_live_10_06_2022Article.php#2025
      Bindings
      • 0: LOC
      Backtrace
      • 13. app/Models/Article.php:2025
      • 14. app/Http/Controllers/ArticleController.php:2112
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select count(*) as total_count, content_type_access_id as access_type from journal_access where content_type_id = '109063' and content_type = 'a' and ( (from_date <= CURDATE() and to_date >= CURDATE() and perpetual= 0) or (from_date is null and to_date is null and perpetual= 1) )
      2.66msalphaeurekaselec_live_10_06_2022ContentAccess.php#647
      Backtrace
      • 11. app/Models/ContentAccess.php:647
      • 12. app/Http/Controllers/ArticleController.php:2186
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select count(*) as total_count, content_type_access_id as access_type from journal_access where content_type_id = '10633' and content_type = 'i' and ( (from_date <= CURDATE() and to_date >= CURDATE() and perpetual= 0) or (from_date is null and to_date is null and perpetual= 1) )
      2.27msalphaeurekaselec_live_10_06_2022ContentAccess.php#647
      Backtrace
      • 11. app/Models/ContentAccess.php:647
      • 12. app/Http/Controllers/ArticleController.php:2207
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select count(*) as total_count, content_type_access_id as access_type from journal_access where content_type_id = '2990' and content_type = 'v' and ( (from_date <= CURDATE() and to_date >= CURDATE() and perpetual= 0) or (from_date is null and to_date is null and perpetual= 1) )
      2msalphaeurekaselec_live_10_06_2022ContentAccess.php#647
      Backtrace
      • 11. app/Models/ContentAccess.php:647
      • 12. app/Http/Controllers/ArticleController.php:2231
      • 13. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 14. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Trial Access" as access_base_text, CASE j.type WHEN 111 THEN true ELSE false END as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"volume" as access_level,"" as issue_id,"" as article_id from `user_access_journal_volume_trail` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.volume_id = 2990) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Subscribed" as access_base_text, false as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"volume" as access_level,"" as issue_id,"" as article_id from `user_access_journal_volume_corporate` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.volume_id = 2990) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Token Based Access" as access_base_text, false as terms_popup, "R" as content_download_type, j.uc_id as restricted_user_access_key, "v" as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"volume" as access_level,"" as issue_id,"" as article_id from `user_access_journal_volume_token` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.volume_id = 2990)
      64.38msalphaeurekaselec_live_10_06_2022UserAccess.php#1266
      Backtrace
      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ArticleController.php:2272
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Trial Access" as access_base_text, CASE j.type WHEN 111 THEN true ELSE false END as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"issue" as access_level,j.issue_id,"" as article_id from `user_access_issue_trail` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.issue_id = 10633) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Subscribed" as access_base_text, false as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"issue" as access_level,j.issue_id,"" as article_id from `user_access_issue_corporate` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.issue_id = 10633) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Token Based Access" as access_base_text, false as terms_popup, "R" as content_download_type, j.uc_id as restricted_user_access_key, "v" as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"issue" as access_level,j.issue_id,"" as article_id from `user_access_issue_token` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.issue_id = 10633)
      1.67msalphaeurekaselec_live_10_06_2022UserAccess.php#1266
      Backtrace
      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ArticleController.php:2297
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Trial Access" as access_base_text, CASE j.type WHEN 111 THEN true ELSE false END as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"article" as access_level, j.issue_id, j.article_id from `user_access_article_trail` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.article_id = 109063) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Subscribed" as access_base_text, false as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"article" as access_level, j.issue_id, j.article_id from `user_access_article_corporate` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.article_id = 109063) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Token Based Access" as access_base_text, false as terms_popup, "R" as content_download_type, j.uc_id as restricted_user_access_key, "v" as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"article" as access_level, j.issue_id, j.article_id from `user_access_article_token` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316574772 and j.to_ip >=316574772 )) and ((j.from_date <= 1740774773 and j.to_date >= 1740774773 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.article_id = 109063)
      960μsalphaeurekaselec_live_10_06_2022UserAccess.php#1266
      Backtrace
      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ArticleController.php:2329
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `article` where `first_page` < '477' and is_uploaded = 1 and issue_id = 10633 order by cast(first_page as SIGNED) desc limit 1
      730μsalphaeurekaselec_live_10_06_2022Article.php#1819
      Bindings
      • 0: 477
      Backtrace
      • 14. app/Models/Article.php:1819
      • 15. app/Http/Controllers/ArticleController.php:2470
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select * from `article` where `last_page` > '489' and is_uploaded = 1 and issue_id = 10633 order by cast(first_page as SIGNED) asc limit 1
      600μsalphaeurekaselec_live_10_06_2022Article.php#1831
      Bindings
      • 0: 489
      Backtrace
      • 14. app/Models/Article.php:1831
      • 15. app/Http/Controllers/ArticleController.php:2472
      • 16. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 17. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select `language_id` from `multilanguage` where `short_code` = 'en'
      250μsalphaeurekaselec_live_10_06_2022ArticleController.php#2497
      Bindings
      • 0: en
      Backtrace
      • 14. app/Http/Controllers/ArticleController.php:2497
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
      • 18. vendor/laravel/framework/src/Illuminate/Routing/Route.php:206
    • select `source_lang_label`, `target_lang_label` from `multilanguage_labels` where `target_lang_id` = 1
      310μsalphaeurekaselec_live_10_06_2022MultiLanguage.php#23
      Bindings
      • 0: 1
      Backtrace
      • 13. app/Models/MultiLanguage.php:23
      • 14. app/Http/Controllers/ArticleController.php:2498
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select `id` from `multilanguage_article` where `article_id` = 109063 limit 1
      4.03msalphaeurekaselec_live_10_06_2022ArticleController.php#2506
      Bindings
      • 0: 109063
      Backtrace
      • 16. app/Http/Controllers/ArticleController.php:2506
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 18. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 19. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
      • 20. vendor/laravel/framework/src/Illuminate/Routing/Route.php:206
    • select b.banner_link, b.banner_name, b.banner_script, b.banner_remarks, b.banner_file_name, b.banner_placement, bd.content_type, bd.content_id from `tbl_banner` as `b` inner join `tbl_banner_detail` as `bd` on `bd`.`banner_id` = `b`.`banner_id` inner join `users` as `u` on `u`.`id` = `b`.`updated_by` inner join `journal` as `j` on `j`.`journal_id` = `bd`.`content_id` where `b`.`banner_journal` = 1 and `bd`.`content_type` = 'J' and `bd`.`content_id` = 48 and `b`.`banner_from_date` <= 1740774773 and `b`.`banner_to_date` >= 1740774773 and `b`.`banner_status` = 'A' order by `b`.`banner_id` desc
      1.66msalphaeurekaselec_live_10_06_2022Banner.php#95
      Bindings
      • 0: 1
      • 1: J
      • 2: 48
      • 3: 1740774773
      • 4: 1740774773
      • 5: A
      Backtrace
      • 13. app/Models/Banner.php:95
      • 14. app/Http/helpers.php:404
      • 17. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 18. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
    • select b.banner_link, b.banner_name, b.banner_script, b.banner_remarks, b.banner_file_name, b.banner_placement, bd.content_type, bd.content_id from `tbl_banner` as `b` inner join `tbl_banner_detail` as `bd` on `bd`.`banner_id` = `b`.`banner_id` inner join `users` as `u` on `u`.`id` = `b`.`updated_by` inner join `journal` as `j` on `j`.`journal_id` = `bd`.`content_id` where `b`.`banner_journal` = 1 and `bd`.`content_type` = 'J' and `bd`.`content_id` = 48 and `b`.`banner_from_date` <= 1740774773 and `b`.`banner_to_date` >= 1740774773 and `b`.`banner_status` = 'A' order by `b`.`banner_id` desc
      6.24msalphaeurekaselec_live_10_06_2022Banner.php#95
      Bindings
      • 0: 1
      • 1: J
      • 2: 48
      • 3: 1740774773
      • 4: 1740774773
      • 5: A
      Backtrace
      • 13. app/Models/Banner.php:95
      • 14. app/Http/helpers.php:404
      • 17. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 18. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
    • select count(*) as aggregate from `uc_cart_products` where cart_id='a69f711c54fd44f6f1e2c5738dc8977d'
      2.7msalphaeurekaselec_live_10_06_2022Cart.php#271
      Backtrace
      • 15. app/Models/Cart.php:271
      • 16. view::layouts._header:291
      • 18. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 20. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
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        ClearShow all
        Date ↕MethodURLData
        #12025-02-28 20:32:53GET/article/109063414361