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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Review Article

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

Author(s): Qiuyun Zhang*, Yutao Zhang, Jingsong Cheng, Hu Li* and Peihua Ma

Volume 24, Issue 16, 2020

Page: [1876 - 1891] Pages: 16

DOI: 10.2174/1385272824999200726230556

Price: $65

Abstract

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

Keywords: Metal-organic frameworks, heterogeneous catalysis, biofuels, biodiesel, recyclability, MILs-based catalysts.

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