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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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The Synthesis of New Selenium-containing Heterocycles by the Oxidation Reaction of 2,4-Diaryltetrahydro-4H-selenochromenes

Author(s): Dmitriy Yurievich Direnko*, Boris Ivanovich Drevko and Yaroslav Borisovich Drevko

Volume 24, Issue 15, 2020

Page: [1663 - 1668] Pages: 6

DOI: 10.2174/1385272824999200720165656

Price: $65

Abstract

We have explored the reactions of tetrahydro-4H-selenochromenes in the presence of phosphoric pentachloride, and synthesized new condensate aroylbenzoselenophenes. During the reactions, tetrahydro-4H-selenochromenes with phosphoric pentachloride underwent oxidative aromatization and nucleophilic substitution for a chlorine atom of one of the protons in the alicyclic fragment. Also, the narrowing of the heterocyclic fragment occurred as in synthesized selenium-containing compounds earlier transformed into the corresponding condensate aroylbenzoselenophenes.

Keywords: Synthesis, heterocycles, 2, 4-diaryltetrahydro-4H-selenochromenes, aroylbenzoselenophenes, 1, 5-diketones, pummerer rearrangement.

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