Abstract
2-((E)-((4-((4-methoxyphenyl)ethynyl)phenyl)imino)methyl-4-((E)phenyldiazenyl)phenol (1) have been synthesized and characterized. X-ray single crystal diffraction study of the compound 1 reveal a monoclinic structure. Room temperature luminescence is observed for 1 in CH2Cl2 solution due to π* → π transition. The SHG efficiency by Kurtz powder technique indicating the compound 1 displayed the second harmonic generation (SHG) property.
Keywords: NLO properties, photoluminescence, Schiff base, X-ray crystallography, NMR spectra, TGA.
Graphical Abstract
[http://dx.doi.org/10.1016/j.inoche.2004.09.017]
[http://dx.doi.org/10.1039/C8DT02278J] [PMID: 30046781]
[http://dx.doi.org/10.1039/C8NJ02657B]
[http://dx.doi.org/10.1016/j.eurpolymj.2007.07.037]
[http://dx.doi.org/10.1016/j.measurement.2016.05.012]
[http://dx.doi.org/10.3390/91000815] [PMID: 18007481]
[http://dx.doi.org/10.1039/c2dt30702b] [PMID: 22547326]
[http://dx.doi.org/10.1039/c1nj20618d]
[http://dx.doi.org/10.1016/j.aca.2012.05.022] [PMID: 22713922]
[http://dx.doi.org/10.1039/C1DT11295C] [PMID: 22005842]
[http://dx.doi.org/10.1039/C0CC04113K] [PMID: 21170447]
[http://dx.doi.org/10.1016/S0022-328X(98)01106-1]
[http://dx.doi.org/10.1021/ol0483549] [PMID: 15469363]
[http://dx.doi.org/10.1007/s10895-016-2020-z]
[http://dx.doi.org/10.1107/S0108767307043930] [PMID: 18156677]
[http://dx.doi.org/10.1016/j.ica.2016.01.042]
[http://dx.doi.org/10.1016/j.molstruc.2014.05.078]
[http://dx.doi.org/10.1039/c2dt31143g] [PMID: 22858862]
[http://dx.doi.org/10.1016/j.molstruc.2018.08.085]
[http://dx.doi.org/10.1016/j.saa.2006.08.037]
[http://dx.doi.org/10.1039/C5NJ00571J]
[http://dx.doi.org/10.1021/jo960538g] [PMID: 11667517]
[http://dx.doi.org/10.1016/S1387-7003(03)00157-6]