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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Letter Article

Trihaloisocyanuric Acids: Useful Reagents for Conversion of Benzaldehydes into Benzylidene Dihalides under Appel Conditions

Author(s): Haryadylla da C. Sindra, Carlos Vinícius P. dos Santos and Marcio C.S. de Mattos*

Volume 17, Issue 8, 2020

Page: [590 - 595] Pages: 6

DOI: 10.2174/1570178617666200121110618

Price: $65

Abstract

The reaction of substituted benzaldehydes with tribromoisocyanuric acid and triphenylphosphine led to the corresponding benzylidene dibromides (95-99%). Similar reaction using trichloroisocyanuric acid produced benzylidene dichlorides (38-96%).

Keywords: Carbonyl compounds, gem-dibromides, gem-dichlorides, halogenation, substituted benzaldehydes, triphenylphosphine.

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